Deuterium hyperfine structure measurements and theory for CD3Br

S. G. Kukolich; C. D. Cogley

doi:10.1063/1.443206

Deuterium hyperfine structure measurements and theory for CD₃Br

S. G. Kukolich, C. D. Cogley

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Hyperfine structure on the J=1→0, F₁ = 3/2 transitions in CH₃ ⁷⁹Br, CH₃ ⁸¹Br, and CD ₃ ⁷⁹Br was measured with one-cavity and two-cavity beam maser spectrometers. The resolution for the measurements was approximately 2 kHz and most hyperfine structure components were completely resolved. Deuterium quadrupole coupling eQq₁₂=178.5±3 kHz along the C-D bond and other parameters were obtained. In the theory section, formulas for the hyperfine interaction strengths with three equivalent spins are presented and reviewed. Deuterium quadrupole coupling in other C-D bond systems is discussed.

Original language	English (US)
Pages (from-to)	1685-1691
Number of pages	7
Journal	The Journal of chemical physics
Volume	76
Issue number	4
DOIs	https://doi.org/10.1063/1.443206
State	Published - 1982

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.443206

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title = "Deuterium hyperfine structure measurements and theory for CD3Br",

abstract = "Hyperfine structure on the J=1→0, F1 = 3/2 transitions in CH3 79Br, CH3 81Br, and CD 3 79Br was measured with one-cavity and two-cavity beam maser spectrometers. The resolution for the measurements was approximately 2 kHz and most hyperfine structure components were completely resolved. Deuterium quadrupole coupling eQq12=178.5±3 kHz along the C-D bond and other parameters were obtained. In the theory section, formulas for the hyperfine interaction strengths with three equivalent spins are presented and reviewed. Deuterium quadrupole coupling in other C-D bond systems is discussed.",

author = "Kukolich, {S. G.} and Cogley, {C. D.}",

year = "1982",

doi = "10.1063/1.443206",

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volume = "76",

pages = "1685--1691",

journal = "The Journal of chemical physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

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T1 - Deuterium hyperfine structure measurements and theory for CD3Br

AU - Kukolich, S. G.

AU - Cogley, C. D.

PY - 1982

Y1 - 1982

N2 - Hyperfine structure on the J=1→0, F1 = 3/2 transitions in CH3 79Br, CH3 81Br, and CD 3 79Br was measured with one-cavity and two-cavity beam maser spectrometers. The resolution for the measurements was approximately 2 kHz and most hyperfine structure components were completely resolved. Deuterium quadrupole coupling eQq12=178.5±3 kHz along the C-D bond and other parameters were obtained. In the theory section, formulas for the hyperfine interaction strengths with three equivalent spins are presented and reviewed. Deuterium quadrupole coupling in other C-D bond systems is discussed.

AB - Hyperfine structure on the J=1→0, F1 = 3/2 transitions in CH3 79Br, CH3 81Br, and CD 3 79Br was measured with one-cavity and two-cavity beam maser spectrometers. The resolution for the measurements was approximately 2 kHz and most hyperfine structure components were completely resolved. Deuterium quadrupole coupling eQq12=178.5±3 kHz along the C-D bond and other parameters were obtained. In the theory section, formulas for the hyperfine interaction strengths with three equivalent spins are presented and reviewed. Deuterium quadrupole coupling in other C-D bond systems is discussed.

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JF - The Journal of chemical physics

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Deuterium hyperfine structure measurements and theory for CD₃Br

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