Design, synthesis, nonlinear spectroscopy and applications of two-photon absorbing molecules

D. Beljonne; J. L. Bredas; B. H. Cumpston; J. Ehrlich; L. Erskine; A. A. Heikal; Z. Y. Hu; T. Kogej; I. Y.S. Lee; S. R. Marder; J. W. Perry; H. Rockel; S. Thayumanavan; X. L. Wu

Design, synthesis, nonlinear spectroscopy and applications of two-photon absorbing molecules

D. Beljonne, J. L. Bredas, B. H. Cumpston, J. Ehrlich, L. Erskine, A. A. Heikal, Z. Y. Hu, T. Kogej, I. Y.S. Lee, S. R. Marder, J. W. Perry, H. Rockel, S. Thayumanavan, X. L. Wu

Research output: Contribution to journal › Conference article › peer-review

Abstract

Large two-photon absorptivities in bis-donor diphenylpolyene derivatives were observed to determine their two-photon absorption spectra and to examine structure/two-photon spectra relationships. A simple bis donor-substituted stilbene had exceptionally large two-photon absorption cross section. Two-photon excitation of a variety of bis-donor diphenylpolyene derivatives in the presence of acrylate monomers led to the formation of polymers. With the two-photon absorbing molecule dissolved at 1% concentration in triacrylate monomer, an excitation of approximately 600 nm with an intensity of approximately 100 MW/cm² yielded cross-linked polymer spots.

Original language	English (US)
Pages (from-to)	497
Number of pages	1
Journal	American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume	38
Issue number	2
State	Published - Sep 1997
Externally published	Yes
Event	Proceedings of the 1997 Las Vegas ACS Meeting - Las Vegas, NV, USA Duration: Sep 7 1997 → Sep 12 1997

ASJC Scopus subject areas

Polymers and Plastics

Cite this

Beljonne, D., Bredas, J. L., Cumpston, B. H., Ehrlich, J., Erskine, L., Heikal, A. A., Hu, Z. Y., Kogej, T., Lee, I. Y. S., Marder, S. R., Perry, J. W., Rockel, H., Thayumanavan, S., & Wu, X. L. (1997). Design, synthesis, nonlinear spectroscopy and applications of two-photon absorbing molecules. American Chemical Society, Polymer Preprints, Division of Polymer Chemistry, 38(2), 497.

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title = "Design, synthesis, nonlinear spectroscopy and applications of two-photon absorbing molecules",

abstract = "Large two-photon absorptivities in bis-donor diphenylpolyene derivatives were observed to determine their two-photon absorption spectra and to examine structure/two-photon spectra relationships. A simple bis donor-substituted stilbene had exceptionally large two-photon absorption cross section. Two-photon excitation of a variety of bis-donor diphenylpolyene derivatives in the presence of acrylate monomers led to the formation of polymers. With the two-photon absorbing molecule dissolved at 1% concentration in triacrylate monomer, an excitation of approximately 600 nm with an intensity of approximately 100 MW/cm2 yielded cross-linked polymer spots.",

author = "D. Beljonne and Bredas, {J. L.} and Cumpston, {B. H.} and J. Ehrlich and L. Erskine and Heikal, {A. A.} and Hu, {Z. Y.} and T. Kogej and Lee, {I. Y.S.} and Marder, {S. R.} and Perry, {J. W.} and H. Rockel and S. Thayumanavan and Wu, {X. L.}",

year = "1997",

month = sep,

language = "English (US)",

volume = "38",

pages = "497",

journal = "American Chemical Society, Polymer Preprints, Division of Polymer Chemistry",

issn = "0032-3934",

number = "2",

note = "Proceedings of the 1997 Las Vegas ACS Meeting ; Conference date: 07-09-1997 Through 12-09-1997",

}

TY - JOUR

T1 - Design, synthesis, nonlinear spectroscopy and applications of two-photon absorbing molecules

AU - Beljonne, D.

AU - Bredas, J. L.

AU - Cumpston, B. H.

AU - Ehrlich, J.

AU - Erskine, L.

AU - Heikal, A. A.

AU - Hu, Z. Y.

AU - Kogej, T.

AU - Lee, I. Y.S.

AU - Marder, S. R.

AU - Perry, J. W.

AU - Rockel, H.

AU - Thayumanavan, S.

AU - Wu, X. L.

PY - 1997/9

Y1 - 1997/9

N2 - Large two-photon absorptivities in bis-donor diphenylpolyene derivatives were observed to determine their two-photon absorption spectra and to examine structure/two-photon spectra relationships. A simple bis donor-substituted stilbene had exceptionally large two-photon absorption cross section. Two-photon excitation of a variety of bis-donor diphenylpolyene derivatives in the presence of acrylate monomers led to the formation of polymers. With the two-photon absorbing molecule dissolved at 1% concentration in triacrylate monomer, an excitation of approximately 600 nm with an intensity of approximately 100 MW/cm2 yielded cross-linked polymer spots.

AB - Large two-photon absorptivities in bis-donor diphenylpolyene derivatives were observed to determine their two-photon absorption spectra and to examine structure/two-photon spectra relationships. A simple bis donor-substituted stilbene had exceptionally large two-photon absorption cross section. Two-photon excitation of a variety of bis-donor diphenylpolyene derivatives in the presence of acrylate monomers led to the formation of polymers. With the two-photon absorbing molecule dissolved at 1% concentration in triacrylate monomer, an excitation of approximately 600 nm with an intensity of approximately 100 MW/cm2 yielded cross-linked polymer spots.

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UR - http://www.scopus.com/inward/citedby.url?scp=0031232659&partnerID=8YFLogxK

M3 - Conference article

AN - SCOPUS:0031232659

SN - 0032-3934

VL - 38

SP - 497

JO - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

JF - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

IS - 2

T2 - Proceedings of the 1997 Las Vegas ACS Meeting

Y2 - 7 September 1997 through 12 September 1997

ER -

Design, synthesis, nonlinear spectroscopy and applications of two-photon absorbing molecules

Abstract

ASJC Scopus subject areas

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