Design and performance of a sensor system for detection of multiple chemicals using an external cavity quantum cascade laser

  • Mark C. Phillips
  • , Matthew S. Taubman
  • , Bruce E. Bernacki
  • , Bret D. Cannon
  • , John T. Schiffern
  • , Tanya L. Myers

Research output: Chapter in Book/Report/Conference proceedingConference contribution

30 Scopus citations

Abstract

We describe the performance of a sensor system designed for simultaneous detection of multiple chemicals with both broad and narrow absorption features. The sensor system consists of a broadly tunable external cavity quantum cascade laser (ECQCL), multi-pass Herriott cell, and custom low-noise electronics. The ECQCL features a fast wavelength tuning rate of 2265 cm-1/s (15660 nm/s) over the range of 1150-1270 cm-1 (7.87-8.70 μm), which permits detection of molecules with broad absorption features and dynamic concentrations, while the 0.2 cm-1 spectral resolution of the ECQCL system allows measurement of small molecules with atmospherically broadened absorption lines. High-speed amplitude modulation and low-noise electronics are used to improve the ECQCL performance for direct absorption measurements. We demonstrate simultaneous detection of Freon-134a (1,1,1,2-tetrafluoroethane), ammonia (NH3), and nitrous oxide (N2O) at low-ppb concentrations in field measurements of atmospheric chemical releases from a point source.

Original languageEnglish (US)
Title of host publicationQuantum Sensing and Nanophotonic Devices VII
DOIs
StatePublished - 2010
Externally publishedYes
EventQuantum Sensing and Nanophotonic Devices VII - San Francisco, CA, United States
Duration: Jan 24 2010Jan 28 2010

Publication series

NameProceedings of SPIE - The International Society for Optical Engineering
Volume7608
ISSN (Print)0277-786X

Conference

ConferenceQuantum Sensing and Nanophotonic Devices VII
Country/TerritoryUnited States
CitySan Francisco, CA
Period1/24/101/28/10

Keywords

  • Infrared spectroscopy
  • Quantum cascade laser
  • Tunable laser

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Computer Science Applications
  • Applied Mathematics
  • Electrical and Electronic Engineering

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