Dendrimers based on thermally reversible furan-maleimide Diels-Alder adducts

Michael L. Szalai; Dominic V. McGrath; David R. Wheeler; Thomas Zifer; James R. McElhanon

doi:10.1021/ma062093w

Dendrimers based on thermally reversible furan-maleimide Diels-Alder adducts

Michael L. Szalai, Dominic V. McGrath, David R. Wheeler, Thomas Zifer, James R. McElhanon

Research output: Contribution to journal › Article › peer-review

100 Scopus citations

Abstract

Thermally labile dendrimers based on the reversible furan-maleimide Diels-Alder reaction are described. First through fourth generation benzyl aryl ether based dendrons 3a-d that contained furan moieties at their focal point were allowed to react with bismaleimide central linker 4 to provide the corresponding dendrimers 5-8. Thermal degradation and reassembly of these dendrimers were studied under a variety of conditions and monitored by GPC and NMR.

Original language	English (US)
Pages (from-to)	818-823
Number of pages	6
Journal	Macromolecules
Volume	40
Issue number	4
DOIs	https://doi.org/10.1021/ma062093w
State	Published - Feb 20 2007

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/ma062093w

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abstract = "Thermally labile dendrimers based on the reversible furan-maleimide Diels-Alder reaction are described. First through fourth generation benzyl aryl ether based dendrons 3a-d that contained furan moieties at their focal point were allowed to react with bismaleimide central linker 4 to provide the corresponding dendrimers 5-8. Thermal degradation and reassembly of these dendrimers were studied under a variety of conditions and monitored by GPC and NMR.",

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AU - Szalai, Michael L.

AU - McGrath, Dominic V.

AU - Wheeler, David R.

AU - Zifer, Thomas

AU - McElhanon, James R.

PY - 2007/2/20

Y1 - 2007/2/20

N2 - Thermally labile dendrimers based on the reversible furan-maleimide Diels-Alder reaction are described. First through fourth generation benzyl aryl ether based dendrons 3a-d that contained furan moieties at their focal point were allowed to react with bismaleimide central linker 4 to provide the corresponding dendrimers 5-8. Thermal degradation and reassembly of these dendrimers were studied under a variety of conditions and monitored by GPC and NMR.

AB - Thermally labile dendrimers based on the reversible furan-maleimide Diels-Alder reaction are described. First through fourth generation benzyl aryl ether based dendrons 3a-d that contained furan moieties at their focal point were allowed to react with bismaleimide central linker 4 to provide the corresponding dendrimers 5-8. Thermal degradation and reassembly of these dendrimers were studied under a variety of conditions and monitored by GPC and NMR.

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Dendrimers based on thermally reversible furan-maleimide Diels-Alder adducts

Abstract

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