The He I photoelectron spectra of (η5-C5H5)Mn(CO)2HSiHPh2, (η5-C5H4CH3)Mn(CO)2HSiHPh2, and (η5-C5(CH3)5)Mn(CO)2HSiHPh2 (Ph is C6H5) are compared to observe the effect of cyclopentadienyl ring methylation on the extent of Si-H bond interaction with the transition metal in these complexes.
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry