Cyclopentadienyl Ring Methylatlon and Its Effect on Si-H Bond Activation in (η5-C5H5-n(CH3)n)mn(co)2hsih(cehs)2 (n = 0, 1, 5) complexes

Dennis L. Lichtenbergerc; Anjana Rai-Chaudhuri

doi:10.1021/om00119a047

Cyclopentadienyl Ring Methylatlon and Its Effect on Si-H Bond Activation in (η⁵-C₅H_5-n(CH₃)n)mn(co)₂hsih(cehs)₂ (n = 0, 1, 5) complexes

Dennis L. Lichtenbergerc, Anjana Rai-Chaudhuri

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

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Abstract

The He I photoelectron spectra of (η⁵-C₅H₅)Mn(CO)₂HSiHPh₂, (η⁵-C₅H₄CH₃)Mn(CO)₂HSiHPh₂, and (η⁵-C₅(CH₃)₅)Mn(CO)₂HSiHPh₂ (Ph is C₆H₅) are compared to observe the effect of cyclopentadienyl ring methylation on the extent of Si-H bond interaction with the transition metal in these complexes.

Original language	English (US)
Pages (from-to)	1686-1690
Number of pages	5
Journal	Organometallics
Volume	9
Issue number	5
DOIs	https://doi.org/10.1021/om00119a047
State	Published - 1990

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Cyclopentadienyl Ring Methylatlon and Its Effect on Si-H Bond Activation in (η5-C5H5-n(CH3)n)mn(co)2hsih(cehs)2 (n = 0, 1, 5) complexes",

abstract = "The He I photoelectron spectra of (η5-C5H5)Mn(CO)2HSiHPh2, (η5-C5H4CH3)Mn(CO)2HSiHPh2, and (η5-C5(CH3)5)Mn(CO)2HSiHPh2 (Ph is C6H5) are compared to observe the effect of cyclopentadienyl ring methylation on the extent of Si-H bond interaction with the transition metal in these complexes.",

author = "Lichtenbergerc, {Dennis L.} and Anjana Rai-Chaudhuri",

year = "1990",

doi = "10.1021/om00119a047",

language = "English (US)",

volume = "9",

pages = "1686--1690",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

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T1 - Cyclopentadienyl Ring Methylatlon and Its Effect on Si-H Bond Activation in (η5-C5H5-n(CH3)n)mn(co)2hsih(cehs)2 (n = 0, 1, 5) complexes

AU - Lichtenbergerc, Dennis L.

AU - Rai-Chaudhuri, Anjana

PY - 1990

Y1 - 1990

N2 - The He I photoelectron spectra of (η5-C5H5)Mn(CO)2HSiHPh2, (η5-C5H4CH3)Mn(CO)2HSiHPh2, and (η5-C5(CH3)5)Mn(CO)2HSiHPh2 (Ph is C6H5) are compared to observe the effect of cyclopentadienyl ring methylation on the extent of Si-H bond interaction with the transition metal in these complexes.

AB - The He I photoelectron spectra of (η5-C5H5)Mn(CO)2HSiHPh2, (η5-C5H4CH3)Mn(CO)2HSiHPh2, and (η5-C5(CH3)5)Mn(CO)2HSiHPh2 (Ph is C6H5) are compared to observe the effect of cyclopentadienyl ring methylation on the extent of Si-H bond interaction with the transition metal in these complexes.

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U2 - 10.1021/om00119a047

DO - 10.1021/om00119a047

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SP - 1686

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JO - Organometallics

JF - Organometallics

IS - 5

ER -

Cyclopentadienyl Ring Methylatlon and Its Effect on Si-H Bond Activation in (η⁵-C₅H_5-n(CH₃)n)mn(co)₂hsih(cehs)₂ (n = 0, 1, 5) complexes

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