Copper(i)/(II)-redox triggered efficient and green rare-earth separation using a heterometallic metal-organic framework

Yue Qiao Hu; Tao Zhang; Mu Qing Li; Yanyan Wang; Zhiping Zheng; Yan Zhen Zheng

doi:10.1039/c6gc02833k

Copper(i)/(II)-redox triggered efficient and green rare-earth separation using a heterometallic metal-organic framework

Yue Qiao Hu, Tao Zhang, Mu Qing Li, Yanyan Wang, Zhiping Zheng, Yan Zhen Zheng

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

A low-cost, highly efficient and green approach (free of ammonia) to enrich Nd from other rare-earth (RE) elements was reported by using a mixed Cu-RE metal-organic framework whose structure can selectively crystallize heavier RE elements during a one-pot reaction with isonicotnic acid, CuI and mixed RE sources, and release heavier RE elements via oxidation of the cuprous ions under ambient conditions.

Original language	English (US)
Pages (from-to)	1250-1254
Number of pages	5
Journal	Green Chemistry
Volume	19
Issue number	5
DOIs	https://doi.org/10.1039/c6gc02833k
State	Published - 2017

ASJC Scopus subject areas

Environmental Chemistry
Pollution

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10.1039/c6gc02833k

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abstract = "A low-cost, highly efficient and green approach (free of ammonia) to enrich Nd from other rare-earth (RE) elements was reported by using a mixed Cu-RE metal-organic framework whose structure can selectively crystallize heavier RE elements during a one-pot reaction with isonicotnic acid, CuI and mixed RE sources, and release heavier RE elements via oxidation of the cuprous ions under ambient conditions.",

author = "Hu, {Yue Qiao} and Tao Zhang and Li, {Mu Qing} and Yanyan Wang and Zhiping Zheng and Zheng, {Yan Zhen}",

note = "Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",

year = "2017",

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language = "English (US)",

volume = "19",

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publisher = "Royal Society of Chemistry",

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AU - Hu, Yue Qiao

AU - Zhang, Tao

AU - Li, Mu Qing

AU - Wang, Yanyan

AU - Zheng, Zhiping

AU - Zheng, Yan Zhen

PY - 2017

Y1 - 2017

N2 - A low-cost, highly efficient and green approach (free of ammonia) to enrich Nd from other rare-earth (RE) elements was reported by using a mixed Cu-RE metal-organic framework whose structure can selectively crystallize heavier RE elements during a one-pot reaction with isonicotnic acid, CuI and mixed RE sources, and release heavier RE elements via oxidation of the cuprous ions under ambient conditions.

AB - A low-cost, highly efficient and green approach (free of ammonia) to enrich Nd from other rare-earth (RE) elements was reported by using a mixed Cu-RE metal-organic framework whose structure can selectively crystallize heavier RE elements during a one-pot reaction with isonicotnic acid, CuI and mixed RE sources, and release heavier RE elements via oxidation of the cuprous ions under ambient conditions.

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U2 - 10.1039/c6gc02833k

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Copper(i)/(II)-redox triggered efficient and green rare-earth separation using a heterometallic metal-organic framework

Abstract

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CCDC 1430392: Experimental Crystal Structure Determination

CCDC 1430395: Experimental Crystal Structure Determination

CCDC 1430397: Experimental Crystal Structure Determination

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Copper(i)/(II)-redox triggered efficient and green rare-earth separation using a heterometallic metal-organic framework

Abstract

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Datasets

CCDC 1430392: Experimental Crystal Structure Determination

CCDC 1430395: Experimental Crystal Structure Determination

CCDC 1430397: Experimental Crystal Structure Determination

Cite this