Copper(i)/(II)-redox triggered efficient and green rare-earth separation using a heterometallic metal-organic framework

Yue Qiao Hu; Tao Zhang; Mu Qing Li; Yanyan Wang; Zhiping Zheng; Yan Zhen Zheng

doi:10.1039/c6gc02833k

Copper(i)/(II)-redox triggered efficient and green rare-earth separation using a heterometallic metal-organic framework

Yue Qiao Hu, Tao Zhang, Mu Qing Li, Yanyan Wang, Zhiping Zheng, Yan Zhen Zheng

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

A low-cost, highly efficient and green approach (free of ammonia) to enrich Nd from other rare-earth (RE) elements was reported by using a mixed Cu-RE metal-organic framework whose structure can selectively crystallize heavier RE elements during a one-pot reaction with isonicotnic acid, CuI and mixed RE sources, and release heavier RE elements via oxidation of the cuprous ions under ambient conditions.

Original language	English (US)
Pages (from-to)	1250-1254
Number of pages	5
Journal	Green Chemistry
Volume	19
Issue number	5
DOIs	https://doi.org/10.1039/c6gc02833k
State	Published - 2017

ASJC Scopus subject areas

Environmental Chemistry
Pollution

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10.1039/c6gc02833k

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title = "Copper(i)/(II)-redox triggered efficient and green rare-earth separation using a heterometallic metal-organic framework",

abstract = "A low-cost, highly efficient and green approach (free of ammonia) to enrich Nd from other rare-earth (RE) elements was reported by using a mixed Cu-RE metal-organic framework whose structure can selectively crystallize heavier RE elements during a one-pot reaction with isonicotnic acid, CuI and mixed RE sources, and release heavier RE elements via oxidation of the cuprous ions under ambient conditions.",

author = "Hu, {Yue Qiao} and Tao Zhang and Li, {Mu Qing} and Yanyan Wang and Zhiping Zheng and Zheng, {Yan Zhen}",

note = "Funding Information: This work was supported by the NSFC (21473129, 21620102002), the {"}National Young-1000-Plan{"} program, and the Fundamental Research Funds for the Central Universities. Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/c6gc02833k",

language = "English (US)",

volume = "19",

pages = "1250--1254",

journal = "Green Chemistry",

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T1 - Copper(i)/(II)-redox triggered efficient and green rare-earth separation using a heterometallic metal-organic framework

AU - Hu, Yue Qiao

AU - Zhang, Tao

AU - Li, Mu Qing

AU - Wang, Yanyan

AU - Zheng, Zhiping

AU - Zheng, Yan Zhen

N1 - Funding Information: This work was supported by the NSFC (21473129, 21620102002), the "National Young-1000-Plan" program, and the Fundamental Research Funds for the Central Universities. Publisher Copyright: © 2017 The Royal Society of Chemistry.

PY - 2017

Y1 - 2017

N2 - A low-cost, highly efficient and green approach (free of ammonia) to enrich Nd from other rare-earth (RE) elements was reported by using a mixed Cu-RE metal-organic framework whose structure can selectively crystallize heavier RE elements during a one-pot reaction with isonicotnic acid, CuI and mixed RE sources, and release heavier RE elements via oxidation of the cuprous ions under ambient conditions.

AB - A low-cost, highly efficient and green approach (free of ammonia) to enrich Nd from other rare-earth (RE) elements was reported by using a mixed Cu-RE metal-organic framework whose structure can selectively crystallize heavier RE elements during a one-pot reaction with isonicotnic acid, CuI and mixed RE sources, and release heavier RE elements via oxidation of the cuprous ions under ambient conditions.

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ER -

Copper(i)/(II)-redox triggered efficient and green rare-earth separation using a heterometallic metal-organic framework

Abstract

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CCDC 1430397: Experimental Crystal Structure Determination

CCDC 1430395: Experimental Crystal Structure Determination

CCDC 1430398: Experimental Crystal Structure Determination

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Copper(i)/(II)-redox triggered efficient and green rare-earth separation using a heterometallic metal-organic framework

Abstract

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Datasets

CCDC 1430397: Experimental Crystal Structure Determination

CCDC 1430395: Experimental Crystal Structure Determination

CCDC 1430398: Experimental Crystal Structure Determination

Cite this