Coordination of oxovanadium(v) in an expanded porphyrin macrocycle

Jonathan L. Sessler, Elisa Tomat, Vincent M. Lynch

Research output: Contribution to journalArticlepeer-review

31 Scopus citations


The formation of a dioxovanadium(v) complex of an expanded porphyrin-type Schiff base macrocycle is reported; the tetrapyrrolic ligand undergoes a tautomeric shift which permits a bimodal recognition of the nonspherical cationic guest.

Original languageEnglish (US)
Pages (from-to)4486-4488
Number of pages3
JournalChemical Communications
Issue number43
StatePublished - 2006

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry


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