Chiral symmetry breaking by chemically manipulating statistical fluctuation in crystallization

Shu Ting Wu; Yan Rong Wu; Qing Qing Kang; Hui Zhang; La Sheng Long; Zhiping Zheng; Rong Bin Huang; Lan Sun Zheng

doi:10.1002/anie.200703443

Chiral symmetry breaking by chemically manipulating statistical fluctuation in crystallization

Shu Ting Wu, Yan Rong Wu, Qing Qing Kang, Hui Zhang, La Sheng Long, Zhiping Zheng, Rong Bin Huang, Lan Sun Zheng

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

175 Scopus citations

Abstract

Breaking out: By introducing a relatively stable intermediate to chemically control the nucleation rate, chiral symmetry breaking was achieved in the crystallization of intrinsically chiral helical coordination polymers. The fewer crystal clusters formed, the more pronounced the symmetry breaking (see picture). (Graph Presented)

Original language	English (US)
Pages (from-to)	8475-8479
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	44
DOIs	https://doi.org/10.1002/anie.200703443
State	Published - 2007

Keywords

Chiral symmetry breaking
Chirality
Coordination polymers
Enantiomers
Helical structures

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.200703443

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title = "Chiral symmetry breaking by chemically manipulating statistical fluctuation in crystallization",

abstract = "Breaking out: By introducing a relatively stable intermediate to chemically control the nucleation rate, chiral symmetry breaking was achieved in the crystallization of intrinsically chiral helical coordination polymers. The fewer crystal clusters formed, the more pronounced the symmetry breaking (see picture). (Graph Presented)",

keywords = "Chiral symmetry breaking, Chirality, Coordination polymers, Enantiomers, Helical structures",

author = "Wu, {Shu Ting} and Wu, {Yan Rong} and Kang, {Qing Qing} and Hui Zhang and Long, {La Sheng} and Zhiping Zheng and Huang, {Rong Bin} and Zheng, {Lan Sun}",

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T1 - Chiral symmetry breaking by chemically manipulating statistical fluctuation in crystallization

AU - Wu, Shu Ting

AU - Wu, Yan Rong

AU - Kang, Qing Qing

AU - Zhang, Hui

AU - Long, La Sheng

AU - Zheng, Zhiping

AU - Huang, Rong Bin

AU - Zheng, Lan Sun

PY - 2007

Y1 - 2007

N2 - Breaking out: By introducing a relatively stable intermediate to chemically control the nucleation rate, chiral symmetry breaking was achieved in the crystallization of intrinsically chiral helical coordination polymers. The fewer crystal clusters formed, the more pronounced the symmetry breaking (see picture). (Graph Presented)

AB - Breaking out: By introducing a relatively stable intermediate to chemically control the nucleation rate, chiral symmetry breaking was achieved in the crystallization of intrinsically chiral helical coordination polymers. The fewer crystal clusters formed, the more pronounced the symmetry breaking (see picture). (Graph Presented)

KW - Chiral symmetry breaking

KW - Chirality

KW - Coordination polymers

KW - Enantiomers

KW - Helical structures

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U2 - 10.1002/anie.200703443

DO - 10.1002/anie.200703443

M3 - Article

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AN - SCOPUS:36148998372

SN - 1433-7851

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 44

ER -

Chiral symmetry breaking by chemically manipulating statistical fluctuation in crystallization

Abstract

Keywords

ASJC Scopus subject areas

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