Characterization of Poly(xylylenes) with Solid-State 13C Nuclear Magnetic Resonance Spectroscopy

Douglas A. Loy; Roger A. Assink; Gregory M. Jamison; W. Frere McNamara; S. Prabakar; Duane A. Schneider

doi:10.1021/ma00121a016

Characterization of Poly(xylylenes) with Solid-State ¹³C Nuclear Magnetic Resonance Spectroscopy

Douglas A. Loy, Roger A. Assink, Gregory M. Jamison, W. Frere McNamara, S. Prabakar, Duane A. Schneider

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Poly(xylylenes) are an important class of thermoplastics that are readily prepared by thermolysis of [2.2]paracyclophane or xylene precursors to afford xylylene monomers that condense and polymerize on solid surfaces to give polymer films. As most poly(xylylenes) are insoluble due to a high degree of crystallinity, characterization by solid-state nuclear magnetic resonance spectroscopic techniques is necessary. In this paper we describe the preparation of poly(xylylene) (P1), poly(2-ethylxylylene) (P2), poly(2-chloroxylylene) (P3), poly(2,3-dichloroxylylene) (P4), and poly(α,α,α′,α′-tetrafluoroxylylene) (P5) and their characterization using solid-state ¹³C cross polarization magic angle spinning nuclear magnetic resonance (CP MAS NMR) spectroscopy.

Original language	English (US)
Pages (from-to)	5799-5803
Number of pages	5
Journal	Macromolecules
Volume	28
Issue number	17
DOIs	https://doi.org/10.1021/ma00121a016
State	Published - Aug 1 1995
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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abstract = "Poly(xylylenes) are an important class of thermoplastics that are readily prepared by thermolysis of [2.2]paracyclophane or xylene precursors to afford xylylene monomers that condense and polymerize on solid surfaces to give polymer films. As most poly(xylylenes) are insoluble due to a high degree of crystallinity, characterization by solid-state nuclear magnetic resonance spectroscopic techniques is necessary. In this paper we describe the preparation of poly(xylylene) (P1), poly(2-ethylxylylene) (P2), poly(2-chloroxylylene) (P3), poly(2,3-dichloroxylylene) (P4), and poly(α,α,α′,α′-tetrafluoroxylylene) (P5) and their characterization using solid-state 13C cross polarization magic angle spinning nuclear magnetic resonance (CP MAS NMR) spectroscopy.",

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T1 - Characterization of Poly(xylylenes) with Solid-State 13C Nuclear Magnetic Resonance Spectroscopy

AU - Loy, Douglas A.

AU - Assink, Roger A.

AU - Jamison, Gregory M.

AU - McNamara, W. Frere

AU - Prabakar, S.

AU - Schneider, Duane A.

PY - 1995/8/1

Y1 - 1995/8/1

N2 - Poly(xylylenes) are an important class of thermoplastics that are readily prepared by thermolysis of [2.2]paracyclophane or xylene precursors to afford xylylene monomers that condense and polymerize on solid surfaces to give polymer films. As most poly(xylylenes) are insoluble due to a high degree of crystallinity, characterization by solid-state nuclear magnetic resonance spectroscopic techniques is necessary. In this paper we describe the preparation of poly(xylylene) (P1), poly(2-ethylxylylene) (P2), poly(2-chloroxylylene) (P3), poly(2,3-dichloroxylylene) (P4), and poly(α,α,α′,α′-tetrafluoroxylylene) (P5) and their characterization using solid-state 13C cross polarization magic angle spinning nuclear magnetic resonance (CP MAS NMR) spectroscopy.

AB - Poly(xylylenes) are an important class of thermoplastics that are readily prepared by thermolysis of [2.2]paracyclophane or xylene precursors to afford xylylene monomers that condense and polymerize on solid surfaces to give polymer films. As most poly(xylylenes) are insoluble due to a high degree of crystallinity, characterization by solid-state nuclear magnetic resonance spectroscopic techniques is necessary. In this paper we describe the preparation of poly(xylylene) (P1), poly(2-ethylxylylene) (P2), poly(2-chloroxylylene) (P3), poly(2,3-dichloroxylylene) (P4), and poly(α,α,α′,α′-tetrafluoroxylylene) (P5) and their characterization using solid-state 13C cross polarization magic angle spinning nuclear magnetic resonance (CP MAS NMR) spectroscopy.

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Characterization of Poly(xylylenes) with Solid-State ¹³C Nuclear Magnetic Resonance Spectroscopy

Abstract

ASJC Scopus subject areas

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