Bonding in the heavy analogue of hydrogen cyanide: The curious case of bridged HPSi

Valerio Lattanzi; Sven Thorwirth; De Wayne T. Halfen; Leonie Anna Mück; Lucy M. Ziurys; Patrick Thaddeus; Jürgen Gauss; Michael C. McCarthy

doi:10.1002/anie.201001938

Bonding in the heavy analogue of hydrogen cyanide: The curious case of bridged HPSi

Valerio Lattanzi, Sven Thorwirth, De Wayne T. Halfen, Leonie Anna Mück, Lucy M. Ziurys, Patrick Thaddeus, Jürgen Gauss, Michael C. McCarthy

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

chemical equation presented Curiouser and curiouser: By combining high-resolution molecular spectroscopy in the centimeter and millimeter wave regions, and high-level coupled-cluster quantum-chemical calculations, the structure of the HPSi molecule has been determined. The bridged geometry of HPSi is in remarkable contrast to that of the C and/or N analogues, such as HCN/ HNC, HCP, and HNSi, which are all linear.

Original language	English (US)
Pages (from-to)	5661-5664
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	33
DOIs	https://doi.org/10.1002/anie.201001938
State	Published - Aug 2 2010

Keywords

Multiple bonds
Phosphorous
Quantum-chemical calculations
Rotational spectroscopy
Silicon

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.201001938

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title = "Bonding in the heavy analogue of hydrogen cyanide: The curious case of bridged HPSi",

abstract = "chemical equation presented Curiouser and curiouser: By combining high-resolution molecular spectroscopy in the centimeter and millimeter wave regions, and high-level coupled-cluster quantum-chemical calculations, the structure of the HPSi molecule has been determined. The bridged geometry of HPSi is in remarkable contrast to that of the C and/or N analogues, such as HCN/ HNC, HCP, and HNSi, which are all linear.",

keywords = "Multiple bonds, Phosphorous, Quantum-chemical calculations, Rotational spectroscopy, Silicon",

author = "Valerio Lattanzi and Sven Thorwirth and Halfen, \{De Wayne T.\} and M{\"u}ck, \{Leonie Anna\} and Ziurys, \{Lucy M.\} and Patrick Thaddeus and J{\"u}rgen Gauss and McCarthy, \{Michael C.\}",

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T1 - Bonding in the heavy analogue of hydrogen cyanide

T2 - The curious case of bridged HPSi

AU - Lattanzi, Valerio

AU - Thorwirth, Sven

AU - Halfen, De Wayne T.

AU - Mück, Leonie Anna

AU - Ziurys, Lucy M.

AU - Thaddeus, Patrick

AU - Gauss, Jürgen

AU - McCarthy, Michael C.

PY - 2010/8/2

Y1 - 2010/8/2

N2 - chemical equation presented Curiouser and curiouser: By combining high-resolution molecular spectroscopy in the centimeter and millimeter wave regions, and high-level coupled-cluster quantum-chemical calculations, the structure of the HPSi molecule has been determined. The bridged geometry of HPSi is in remarkable contrast to that of the C and/or N analogues, such as HCN/ HNC, HCP, and HNSi, which are all linear.

AB - chemical equation presented Curiouser and curiouser: By combining high-resolution molecular spectroscopy in the centimeter and millimeter wave regions, and high-level coupled-cluster quantum-chemical calculations, the structure of the HPSi molecule has been determined. The bridged geometry of HPSi is in remarkable contrast to that of the C and/or N analogues, such as HCN/ HNC, HCP, and HNSi, which are all linear.

KW - Multiple bonds

KW - Phosphorous

KW - Quantum-chemical calculations

KW - Rotational spectroscopy

KW - Silicon

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 33

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Bonding in the heavy analogue of hydrogen cyanide: The curious case of bridged HPSi

Abstract

Keywords

ASJC Scopus subject areas

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