Beam maser measurements of distortion effects on quadrupole coupling in NH3

David J. Ruben; Stephen G. Kukolich

doi:10.1063/1.1682565

Beam maser measurements of distortion effects on quadrupole coupling in NH₃

David J. Ruben
, Stephen G. Kukolich

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

High resolution (350 Hz) measurements of hyperfine structure on the J =5, K =3 inversion transition in NH, are reported. The average nitrogen quadrupole coupling strength is -393.90k0.08 kHz. This value is in excellent agreement with a value predicted by Hougen's theory.describing distortion corrections to quadrupole coupling in NH, and does not agree with a value calculated without the correction. The line center frequency and other hyperfine structure parameters are given.

Original language	English (US)
Pages (from-to)	3780-3784
Number of pages	5
Journal	The Journal of chemical physics
Volume	61
Issue number	9
DOIs	https://doi.org/10.1063/1.1682565
State	Published - 1974

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

Access to Document

10.1063/1.1682565

Cite this

@article{36fc9cab0648465c8ff94d2355230aee,

title = "Beam maser measurements of distortion effects on quadrupole coupling in NH3",

abstract = "High resolution (350 Hz) measurements of hyperfine structure on the J =5, K =3 inversion transition in NH, are reported. The average nitrogen quadrupole coupling strength is -393.90k0.08 kHz. This value is in excellent agreement with a value predicted by Hougen's theory.describing distortion corrections to quadrupole coupling in NH, and does not agree with a value calculated without the correction. The line center frequency and other hyperfine structure parameters are given.",

author = "Ruben, \{David J.\} and Kukolich, \{Stephen G.\}",

year = "1974",

doi = "10.1063/1.1682565",

language = "English (US)",

volume = "61",

pages = "3780--3784",

journal = "The Journal of chemical physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "9",

}

TY - JOUR

T1 - Beam maser measurements of distortion effects on quadrupole coupling in NH3

AU - Ruben, David J.

AU - Kukolich, Stephen G.

PY - 1974

Y1 - 1974

N2 - High resolution (350 Hz) measurements of hyperfine structure on the J =5, K =3 inversion transition in NH, are reported. The average nitrogen quadrupole coupling strength is -393.90k0.08 kHz. This value is in excellent agreement with a value predicted by Hougen's theory.describing distortion corrections to quadrupole coupling in NH, and does not agree with a value calculated without the correction. The line center frequency and other hyperfine structure parameters are given.

AB - High resolution (350 Hz) measurements of hyperfine structure on the J =5, K =3 inversion transition in NH, are reported. The average nitrogen quadrupole coupling strength is -393.90k0.08 kHz. This value is in excellent agreement with a value predicted by Hougen's theory.describing distortion corrections to quadrupole coupling in NH, and does not agree with a value calculated without the correction. The line center frequency and other hyperfine structure parameters are given.

UR - https://www.scopus.com/pages/publications/4243368613

UR - https://www.scopus.com/pages/publications/4243368613#tab=citedBy

U2 - 10.1063/1.1682565

DO - 10.1063/1.1682565

M3 - Article

AN - SCOPUS:4243368613

SN - 0021-9606

VL - 61

SP - 3780

EP - 3784

JO - The Journal of chemical physics

JF - The Journal of chemical physics

IS - 9

ER -

Beam maser measurements of distortion effects on quadrupole coupling in NH₃

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this