Beam maser measurements of distortion effects on quadrupole coupling in NH3

David J. Ruben; Stephen G. Kukolich

doi:10.1063/1.1682565

Beam maser measurements of distortion effects on quadrupole coupling in NH₃

David J. Ruben, Stephen G. Kukolich

Chemistry and Biochemistry

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11 Scopus citations

Abstract

High resolution (350 Hz) measurements of hyperfine structure on the J =5, K =3 inversion transition in NH, are reported. The average nitrogen quadrupole coupling strength is -393.90k0.08 kHz. This value is in excellent agreement with a value predicted by Hougen's theory.describing distortion corrections to quadrupole coupling in NH, and does not agree with a value calculated without the correction. The line center frequency and other hyperfine structure parameters are given.

Original language	English (US)
Pages (from-to)	3780-3784
Number of pages	5
Journal	The Journal of chemical physics
Volume	61
Issue number	9
DOIs	https://doi.org/10.1063/1.1682565
State	Published - 1974

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.1682565

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title = "Beam maser measurements of distortion effects on quadrupole coupling in NH3",

abstract = "High resolution (350 Hz) measurements of hyperfine structure on the J =5, K =3 inversion transition in NH, are reported. The average nitrogen quadrupole coupling strength is -393.90k0.08 kHz. This value is in excellent agreement with a value predicted by Hougen's theory.describing distortion corrections to quadrupole coupling in NH, and does not agree with a value calculated without the correction. The line center frequency and other hyperfine structure parameters are given.",

author = "Ruben, {David J.} and Kukolich, {Stephen G.}",

year = "1974",

doi = "10.1063/1.1682565",

language = "English (US)",

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pages = "3780--3784",

journal = "The Journal of chemical physics",

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publisher = "American Institute of Physics",

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T1 - Beam maser measurements of distortion effects on quadrupole coupling in NH3

AU - Ruben, David J.

AU - Kukolich, Stephen G.

PY - 1974

Y1 - 1974

N2 - High resolution (350 Hz) measurements of hyperfine structure on the J =5, K =3 inversion transition in NH, are reported. The average nitrogen quadrupole coupling strength is -393.90k0.08 kHz. This value is in excellent agreement with a value predicted by Hougen's theory.describing distortion corrections to quadrupole coupling in NH, and does not agree with a value calculated without the correction. The line center frequency and other hyperfine structure parameters are given.

AB - High resolution (350 Hz) measurements of hyperfine structure on the J =5, K =3 inversion transition in NH, are reported. The average nitrogen quadrupole coupling strength is -393.90k0.08 kHz. This value is in excellent agreement with a value predicted by Hougen's theory.describing distortion corrections to quadrupole coupling in NH, and does not agree with a value calculated without the correction. The line center frequency and other hyperfine structure parameters are given.

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ER -

Beam maser measurements of distortion effects on quadrupole coupling in NH₃

Abstract

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