Abstract
Hyperfine structure on the 110 → 111, 211 → 212, 431 → 432, and 651 → 652 rotational transitions in COF2 was observed with a molecular beam maser spectrometer. The resonance line width (fwhm) ranged from 1.5 kHz on the 111 → 110 transition to 6 kHz on the highest frequency transitions. The diagonal elements of the spin-rotation tensor obtained are Maa = -19.77 ± 0.21 kHz, Mbb = -13.46 ± 0.14 kHz, and Mcc = -7.80 ± 0.26 kHz. Magnetic shielding parameters are calculated from experimental results and comparison is made with other molecules.
Original language | English (US) |
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Pages (from-to) | 4138-4141 |
Number of pages | 4 |
Journal | Journal of the American Chemical Society |
Volume | 95 |
Issue number | 13 |
DOIs | |
State | Published - Jun 27 1973 |
Externally published | Yes |
ASJC Scopus subject areas
- Catalysis
- General Chemistry
- Biochemistry
- Colloid and Surface Chemistry