Atomic structure of the i- R -Cd quasicrystals and consequences for magnetism

T. Yamada, H. Takakura, T. Kong, P. Das, W. T. Jayasekara, A. Kreyssig, G. Beutier, P. C. Canfield, M. De Boissieu, A. I. Goldman

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

We report on the six-dimensional (6D) structural refinement of three members of the i-R-Cd quasicrystals (R = Gd, Dy, Tm) via synchrotron x-ray diffraction from single-grain samples, and show that this series is isostructural to the i-YbCd5.7 quasicrystal. However, our refinements suggest that the R occupancy on the Yb icosahedron sites within the Tsai-type atomic cluster is approximately 80%, with the balance taken up by Cd. Similarities between the i-R-Cd series and i-ScZn7.33, and their differences with i-YbCd5.7 and i-Ca15Cd85, indicate that there are at least two subclasses of Tsai-type icosahedral quasicrystals. We further show from x-ray resonant magnetic scattering (XRMS) measurements on a set of closely related Tb1-xYxCd6 1/1 approximants that the dilution of the magnetic R ions on the icosahedron within the Tsai-type cluster by nonmagnetic Y disrupts the commensurate magnetic ordering in the approximant phase.

Original languageEnglish (US)
Article number060103
JournalPhysical Review B
Volume94
Issue number6
DOIs
StatePublished - Aug 15 2016
Externally publishedYes

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

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