Arylene- and Alkylene-Bridged Siliconates

Douglas A. Loy; James H. Small; Kenneth J. Shea

doi:10.1021/om00028a083

Arylene- and Alkylene-Bridged Siliconates

Douglas A. Loy, James H. Small, Kenneth J. Shea

Research output: Contribution to journal › Comment/debate › peer-review

17 Scopus citations

Abstract

Arylene-bridged pentacoordinate siliconates 3-6 (arylene = 1,4-phenylene, 1,3-phenylene, 4,4′-biphenylene, and 9,10-anthracylene) were prepared from bis(triethoxysilyl)arylene precursors, catechol, and tri-ethylamine in tetrahydrofuran. 1,2-Ethylene and 1,6-hexylene-bridged pentacoordinate siliconates 7 and 8 were prepared from 1,2-bis(trimethoxysilyl)ethane and 1,6-bis(trimethoxysilyl)hexane, respectively. The molecular structure of the 1,4-phenylene-bridged siliconate 3 was determined by X-ray diffraction.

Original language	English (US)
Pages (from-to)	1484-1488
Number of pages	5
Journal	Organometallics
Volume	12
Issue number	4
DOIs	https://doi.org/10.1021/om00028a083
State	Published - 1993
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Arylene- and Alkylene-Bridged Siliconates",

abstract = "Arylene-bridged pentacoordinate siliconates 3-6 (arylene = 1,4-phenylene, 1,3-phenylene, 4,4′-biphenylene, and 9,10-anthracylene) were prepared from bis(triethoxysilyl)arylene precursors, catechol, and tri-ethylamine in tetrahydrofuran. 1,2-Ethylene and 1,6-hexylene-bridged pentacoordinate siliconates 7 and 8 were prepared from 1,2-bis(trimethoxysilyl)ethane and 1,6-bis(trimethoxysilyl)hexane, respectively. The molecular structure of the 1,4-phenylene-bridged siliconate 3 was determined by X-ray diffraction.",

author = "Loy, {Douglas A.} and Small, {James H.} and Shea, {Kenneth J.}",

year = "1993",

doi = "10.1021/om00028a083",

language = "English (US)",

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pages = "1484--1488",

journal = "Organometallics",

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T1 - Arylene- and Alkylene-Bridged Siliconates

AU - Loy, Douglas A.

AU - Small, James H.

AU - Shea, Kenneth J.

PY - 1993

Y1 - 1993

N2 - Arylene-bridged pentacoordinate siliconates 3-6 (arylene = 1,4-phenylene, 1,3-phenylene, 4,4′-biphenylene, and 9,10-anthracylene) were prepared from bis(triethoxysilyl)arylene precursors, catechol, and tri-ethylamine in tetrahydrofuran. 1,2-Ethylene and 1,6-hexylene-bridged pentacoordinate siliconates 7 and 8 were prepared from 1,2-bis(trimethoxysilyl)ethane and 1,6-bis(trimethoxysilyl)hexane, respectively. The molecular structure of the 1,4-phenylene-bridged siliconate 3 was determined by X-ray diffraction.

AB - Arylene-bridged pentacoordinate siliconates 3-6 (arylene = 1,4-phenylene, 1,3-phenylene, 4,4′-biphenylene, and 9,10-anthracylene) were prepared from bis(triethoxysilyl)arylene precursors, catechol, and tri-ethylamine in tetrahydrofuran. 1,2-Ethylene and 1,6-hexylene-bridged pentacoordinate siliconates 7 and 8 were prepared from 1,2-bis(trimethoxysilyl)ethane and 1,6-bis(trimethoxysilyl)hexane, respectively. The molecular structure of the 1,4-phenylene-bridged siliconate 3 was determined by X-ray diffraction.

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Arylene- and Alkylene-Bridged Siliconates

Abstract

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