TY - JOUR
T1 - Apakaochtodenes A and B
T2 - Two tetrahalogenated monoterpenes from the red marine alga Portieria hornemannii
AU - Gunatilaka, A. A.Leslie
AU - Paul, Valerie J.
AU - Park, Peter U.
AU - Puglisi, Melany P.
AU - Gitler, Aaron D.
AU - Eggleston, Drake S.
AU - Haltiwanger, R. Curtis
AU - Kingston, David G.I.
PY - 1999/10
Y1 - 1999/10
N2 - The structure of apakaochtodene A, the minor isomer of two tetrahalogenated ochtodene monoterpenes, isolated from the red marine alga Portieria hornemannii (Lyngbye) Silva has been identified as 6(S(*))bromo- 1,4(S(*)),8(R(*))-trichloro-2(Z)-ochtodene (1) by NMR spectral and X-ray crystallographic analysis. Its geometrical isomer, apakaochtodene B (2), which could not be separated from I and thus characterized as a 95:5 mixture of 2:1 had 1H and 13C NMR spectral characteristics similar to previously known ochtodene (3) and the related tetrahalogenated monoterpene 4.
AB - The structure of apakaochtodene A, the minor isomer of two tetrahalogenated ochtodene monoterpenes, isolated from the red marine alga Portieria hornemannii (Lyngbye) Silva has been identified as 6(S(*))bromo- 1,4(S(*)),8(R(*))-trichloro-2(Z)-ochtodene (1) by NMR spectral and X-ray crystallographic analysis. Its geometrical isomer, apakaochtodene B (2), which could not be separated from I and thus characterized as a 95:5 mixture of 2:1 had 1H and 13C NMR spectral characteristics similar to previously known ochtodene (3) and the related tetrahalogenated monoterpene 4.
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U2 - 10.1021/np9901128
DO - 10.1021/np9901128
M3 - Article
C2 - 10543896
AN - SCOPUS:0032724676
SN - 0163-3864
VL - 62
SP - 1376
EP - 1378
JO - Journal Of Natural Products
JF - Journal Of Natural Products
IS - 10
ER -