An inorganic-organic hybrid composite featuring metal-chalcogenide clusters

Bryan K. Roland; Ware H. Flora; Michael D. Carducci; Neal R. Armstrong; Zhiping Zheng

doi:10.1023/B:JOCL.0000010916.59703.98

An inorganic-organic hybrid composite featuring metal-chalcogenide clusters

Bryan K. Roland, Ware H. Flora, Michael D. Carducci, Neal R. Armstrong, Zhiping Zheng

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

The cluster complex, [Re₆(μ₃-Se) ₈(PEt₃)₅(4-vinylpyridine)](SbF ₆)₂ (1), featuring the face-capped octahedral [Re ₆(μ₃-Se)₈]²⁺ cluster core and site-differentiating triethylphosphine and 4-vinylpyridine ligands has been synthesized and structurally characterized. The complex crystallized in monoclinic space group P2₁ with a = 11.748(1) Å, b = 15.1212(2) Å, c = 19.941(2) Å, α = 90°, β = 94.411(3)°, γ = 90°, V = 3531.8(7) Å³, Z = 2, R1 = 0.0531, wR2 = 0.0774. Copolymerization of styrene with 1 via the polymerizable 4-vinylpyridine ligand afforded a novel inorganic-organic hybrid composite of high molecular weight and a low polydispersity index. Structural integrity of the cluster building block is maintained upon hybrid formation.

Original language	English (US)
Pages (from-to)	449-458
Number of pages	10
Journal	Journal of Cluster Science
Volume	14
Issue number	4
DOIs	https://doi.org/10.1023/B:JOCL.0000010916.59703.98
State	Published - Dec 2003
Externally published	Yes

Keywords

4-vinylpyridine
Organic-inorganic hybrid composites
Polymerization
Rhenium chalcogenide clusters

ASJC Scopus subject areas

General Chemistry
Biochemistry
General Materials Science
Condensed Matter Physics

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10.1023/B:JOCL.0000010916.59703.98

Cite this

@article{029dbd0f882e41fdbce6019aee5161a1,

title = "An inorganic-organic hybrid composite featuring metal-chalcogenide clusters",

abstract = "The cluster complex, [Re6(μ3-Se) 8(PEt3)5(4-vinylpyridine)](SbF 6)2 (1), featuring the face-capped octahedral [Re 6(μ3-Se)8]2+ cluster core and site-differentiating triethylphosphine and 4-vinylpyridine ligands has been synthesized and structurally characterized. The complex crystallized in monoclinic space group P21 with a = 11.748(1) {\AA}, b = 15.1212(2) {\AA}, c = 19.941(2) {\AA}, α = 90°, β = 94.411(3)°, γ = 90°, V = 3531.8(7) {\AA}3, Z = 2, R1 = 0.0531, wR2 = 0.0774. Copolymerization of styrene with 1 via the polymerizable 4-vinylpyridine ligand afforded a novel inorganic-organic hybrid composite of high molecular weight and a low polydispersity index. Structural integrity of the cluster building block is maintained upon hybrid formation.",

keywords = "4-vinylpyridine, Organic-inorganic hybrid composites, Polymerization, Rhenium chalcogenide clusters",

author = "Roland, \{Bryan K.\} and Flora, \{Ware H.\} and Carducci, \{Michael D.\} and Armstrong, \{Neal R.\} and Zhiping Zheng",

note = "Funding Information: We wish to acknowledge the final support by Research Corporation and the University of Arizona. Acknowledgment is also made to the Donors of the Petroleum Research Fund, administered by the American Chemical Society, for partial support of this research. The CCD-based X-ray diffractometer was purchased through an NSF Grant (CHE-96103474, USA).",

year = "2003",

month = dec,

doi = "10.1023/B:JOCL.0000010916.59703.98",

language = "English (US)",

volume = "14",

pages = "449--458",

journal = "Journal of Cluster Science",

issn = "1040-7278",

publisher = "Springer New York",

number = "4",

}

TY - JOUR

T1 - An inorganic-organic hybrid composite featuring metal-chalcogenide clusters

AU - Roland, Bryan K.

AU - Flora, Ware H.

AU - Carducci, Michael D.

AU - Armstrong, Neal R.

AU - Zheng, Zhiping

N1 - Funding Information: We wish to acknowledge the final support by Research Corporation and the University of Arizona. Acknowledgment is also made to the Donors of the Petroleum Research Fund, administered by the American Chemical Society, for partial support of this research. The CCD-based X-ray diffractometer was purchased through an NSF Grant (CHE-96103474, USA).

PY - 2003/12

Y1 - 2003/12

N2 - The cluster complex, [Re6(μ3-Se) 8(PEt3)5(4-vinylpyridine)](SbF 6)2 (1), featuring the face-capped octahedral [Re 6(μ3-Se)8]2+ cluster core and site-differentiating triethylphosphine and 4-vinylpyridine ligands has been synthesized and structurally characterized. The complex crystallized in monoclinic space group P21 with a = 11.748(1) Å, b = 15.1212(2) Å, c = 19.941(2) Å, α = 90°, β = 94.411(3)°, γ = 90°, V = 3531.8(7) Å3, Z = 2, R1 = 0.0531, wR2 = 0.0774. Copolymerization of styrene with 1 via the polymerizable 4-vinylpyridine ligand afforded a novel inorganic-organic hybrid composite of high molecular weight and a low polydispersity index. Structural integrity of the cluster building block is maintained upon hybrid formation.

AB - The cluster complex, [Re6(μ3-Se) 8(PEt3)5(4-vinylpyridine)](SbF 6)2 (1), featuring the face-capped octahedral [Re 6(μ3-Se)8]2+ cluster core and site-differentiating triethylphosphine and 4-vinylpyridine ligands has been synthesized and structurally characterized. The complex crystallized in monoclinic space group P21 with a = 11.748(1) Å, b = 15.1212(2) Å, c = 19.941(2) Å, α = 90°, β = 94.411(3)°, γ = 90°, V = 3531.8(7) Å3, Z = 2, R1 = 0.0531, wR2 = 0.0774. Copolymerization of styrene with 1 via the polymerizable 4-vinylpyridine ligand afforded a novel inorganic-organic hybrid composite of high molecular weight and a low polydispersity index. Structural integrity of the cluster building block is maintained upon hybrid formation.

KW - 4-vinylpyridine

KW - Organic-inorganic hybrid composites

KW - Polymerization

KW - Rhenium chalcogenide clusters

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ER -

An inorganic-organic hybrid composite featuring metal-chalcogenide clusters

Abstract

Keywords

ASJC Scopus subject areas

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CCDC 203886: Experimental Crystal Structure Determination

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An inorganic-organic hybrid composite featuring metal-chalcogenide clusters

Abstract

Keywords

ASJC Scopus subject areas

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Datasets

CCDC 203886: Experimental Crystal Structure Determination

Cite this