An expeditious approach toward the total synthesis of CP-263,114

Jón T. Njardarson; Ivar M. McDonald; David A. Spiegel; Munenori Inoue; John L. Wood

doi:10.1021/ol015979n

An expeditious approach toward the total synthesis of CP-263,114

Jón T. Njardarson, Ivar M. McDonald, David A. Spiegel, Munenori Inoue, John L. Wood

Research output: Contribution to journal › Article › peer-review

58 Scopus citations

Abstract

matrix presented Assembly of the carbocyclic core of CP-263,114 has been accomplished efficiently and in high yield. Key steps include a phenolic oxidation/ intramolecular Diels-Alder sequence, tandem radical cyclization, and the late-stage fragmentation of a densely functionalized isotwistane skeleton.

Original language	English (US)
Pages (from-to)	2435-2438
Number of pages	4
Journal	Organic Letters
Volume	3
Issue number	16
DOIs	https://doi.org/10.1021/ol015979n
State	Published - Aug 9 2001
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol015979n

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title = "An expeditious approach toward the total synthesis of CP-263,114",

abstract = "matrix presented Assembly of the carbocyclic core of CP-263,114 has been accomplished efficiently and in high yield. Key steps include a phenolic oxidation/ intramolecular Diels-Alder sequence, tandem radical cyclization, and the late-stage fragmentation of a densely functionalized isotwistane skeleton.",

author = "Njardarson, {J{\'o}n T.} and McDonald, {Ivar M.} and Spiegel, {David A.} and Munenori Inoue and Wood, {John L.}",

year = "2001",

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doi = "10.1021/ol015979n",

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AU - Njardarson, Jón T.

AU - McDonald, Ivar M.

AU - Spiegel, David A.

AU - Inoue, Munenori

AU - Wood, John L.

PY - 2001/8/9

Y1 - 2001/8/9

N2 - matrix presented Assembly of the carbocyclic core of CP-263,114 has been accomplished efficiently and in high yield. Key steps include a phenolic oxidation/ intramolecular Diels-Alder sequence, tandem radical cyclization, and the late-stage fragmentation of a densely functionalized isotwistane skeleton.

AB - matrix presented Assembly of the carbocyclic core of CP-263,114 has been accomplished efficiently and in high yield. Key steps include a phenolic oxidation/ intramolecular Diels-Alder sequence, tandem radical cyclization, and the late-stage fragmentation of a densely functionalized isotwistane skeleton.

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An expeditious approach toward the total synthesis of CP-263,114

Abstract

ASJC Scopus subject areas

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