An Azido-Cyanide Mixed-Bridged [Fe4Ni4] Single-Molecule Magnet

Jiong Yang; Yi Fei Deng; Xin Yu Zhang; Xiao Yong Chang; Zhi Ping Zheng; Yuan Zhu Zhang

doi:10.1021/acs.inorgchem.8b03559

An Azido-Cyanide Mixed-Bridged [Fe₄Ni₄] Single-Molecule Magnet

Jiong Yang, Yi Fei Deng, Xin Yu Zhang, Xiao Yong Chang, Zhi Ping Zheng, Yuan Zhu Zhang

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

Taking advantages of both azide and cyanide bridges in magnetism and synthesis, an azido-cyanide mixed-bridged octanuclear [Fe^III₄Ni^II₄] SMM of [{(enbzpy)Ni₂(μ_1,1-N₃)₂·(DMF)}{Tp∗Fe(CN)₃}₂]₂·2DMF·14H₂O (1) was explored and characterized, which exhibits slow relaxation of the magnetization and an S = 6 ground state benefit from the end-on azido bridges.

Original language	English (US)
Pages (from-to)	7127-7130
Number of pages	4
Journal	Inorganic Chemistry
Volume	58
Issue number	11
DOIs	https://doi.org/10.1021/acs.inorgchem.8b03559
State	Published - Jun 3 2019

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

Access to Document

10.1021/acs.inorgchem.8b03559

Cite this

@article{3fa1726cfc8044a4b0cd688b10d7b29f,

title = "An Azido-Cyanide Mixed-Bridged [Fe4Ni4] Single-Molecule Magnet",

abstract = "Taking advantages of both azide and cyanide bridges in magnetism and synthesis, an azido-cyanide mixed-bridged octanuclear [FeIII4NiII4] SMM of [\{(enbzpy)Ni2(μ1,1-N3)2·(DMF)\}\{Tp∗Fe(CN)3\}2]2·2DMF·14H2O (1) was explored and characterized, which exhibits slow relaxation of the magnetization and an S = 6 ground state benefit from the end-on azido bridges.",

author = "Jiong Yang and Deng, \{Yi Fei\} and Zhang, \{Xin Yu\} and Chang, \{Xiao Yong\} and Zheng, \{Zhi Ping\} and Zhang, \{Yuan Zhu\}",

note = "Funding Information: This work was supported by the National Natural Science Foundation of China (No. 21671095), Thousand Talents Program-Youth, and start-up fund from SUSTech. Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

year = "2019",

month = jun,

day = "3",

doi = "10.1021/acs.inorgchem.8b03559",

language = "English (US)",

volume = "58",

pages = "7127--7130",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "11",

}

TY - JOUR

T1 - An Azido-Cyanide Mixed-Bridged [Fe4Ni4] Single-Molecule Magnet

AU - Yang, Jiong

AU - Deng, Yi Fei

AU - Zhang, Xin Yu

AU - Chang, Xiao Yong

AU - Zheng, Zhi Ping

AU - Zhang, Yuan Zhu

N1 - Funding Information: This work was supported by the National Natural Science Foundation of China (No. 21671095), Thousand Talents Program-Youth, and start-up fund from SUSTech. Publisher Copyright: © 2019 American Chemical Society.

PY - 2019/6/3

Y1 - 2019/6/3

N2 - Taking advantages of both azide and cyanide bridges in magnetism and synthesis, an azido-cyanide mixed-bridged octanuclear [FeIII4NiII4] SMM of [{(enbzpy)Ni2(μ1,1-N3)2·(DMF)}{Tp∗Fe(CN)3}2]2·2DMF·14H2O (1) was explored and characterized, which exhibits slow relaxation of the magnetization and an S = 6 ground state benefit from the end-on azido bridges.

AB - Taking advantages of both azide and cyanide bridges in magnetism and synthesis, an azido-cyanide mixed-bridged octanuclear [FeIII4NiII4] SMM of [{(enbzpy)Ni2(μ1,1-N3)2·(DMF)}{Tp∗Fe(CN)3}2]2·2DMF·14H2O (1) was explored and characterized, which exhibits slow relaxation of the magnetization and an S = 6 ground state benefit from the end-on azido bridges.

UR - https://www.scopus.com/pages/publications/85066815202

UR - https://www.scopus.com/inward/citedby.url?scp=85066815202&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.8b03559

DO - 10.1021/acs.inorgchem.8b03559

M3 - Article

C2 - 31083933

AN - SCOPUS:85066815202

SN - 0020-1669

VL - 58

SP - 7127

EP - 7130

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 11

ER -

An Azido-Cyanide Mixed-Bridged [Fe₄Ni₄] Single-Molecule Magnet

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this