An Azido-Cyanide Mixed-Bridged [Fe4Ni4] Single-Molecule Magnet

Jiong Yang; Yi Fei Deng; Xin Yu Zhang; Xiao Yong Chang; Zhi Ping Zheng; Yuan Zhu Zhang

doi:10.1021/acs.inorgchem.8b03559

An Azido-Cyanide Mixed-Bridged [Fe₄Ni₄] Single-Molecule Magnet

Jiong Yang, Yi Fei Deng, Xin Yu Zhang, Xiao Yong Chang, Zhi Ping Zheng, Yuan Zhu Zhang

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

Taking advantages of both azide and cyanide bridges in magnetism and synthesis, an azido-cyanide mixed-bridged octanuclear [Fe^III₄Ni^II₄] SMM of [{(enbzpy)Ni₂(μ_1,1-N₃)₂·(DMF)}{Tp∗Fe(CN)₃}₂]₂·2DMF·14H₂O (1) was explored and characterized, which exhibits slow relaxation of the magnetization and an S = 6 ground state benefit from the end-on azido bridges.

Original language	English (US)
Pages (from-to)	7127-7130
Number of pages	4
Journal	Inorganic Chemistry
Volume	58
Issue number	11
DOIs	https://doi.org/10.1021/acs.inorgchem.8b03559
State	Published - Jun 3 2019

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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title = "An Azido-Cyanide Mixed-Bridged [Fe4Ni4] Single-Molecule Magnet",

abstract = "Taking advantages of both azide and cyanide bridges in magnetism and synthesis, an azido-cyanide mixed-bridged octanuclear [FeIII4NiII4] SMM of [{(enbzpy)Ni2(μ1,1-N3)2·(DMF)}{Tp∗Fe(CN)3}2]2·2DMF·14H2O (1) was explored and characterized, which exhibits slow relaxation of the magnetization and an S = 6 ground state benefit from the end-on azido bridges.",

author = "Jiong Yang and Deng, {Yi Fei} and Zhang, {Xin Yu} and Chang, {Xiao Yong} and Zheng, {Zhi Ping} and Zhang, {Yuan Zhu}",

note = "Funding Information: This work was supported by the National Natural Science Foundation of China (No. 21671095), Thousand Talents Program-Youth, and start-up fund from SUSTech. Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

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doi = "10.1021/acs.inorgchem.8b03559",

language = "English (US)",

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T1 - An Azido-Cyanide Mixed-Bridged [Fe4Ni4] Single-Molecule Magnet

AU - Yang, Jiong

AU - Deng, Yi Fei

AU - Zhang, Xin Yu

AU - Chang, Xiao Yong

AU - Zheng, Zhi Ping

AU - Zhang, Yuan Zhu

N1 - Funding Information: This work was supported by the National Natural Science Foundation of China (No. 21671095), Thousand Talents Program-Youth, and start-up fund from SUSTech. Publisher Copyright: © 2019 American Chemical Society.

PY - 2019/6/3

Y1 - 2019/6/3

N2 - Taking advantages of both azide and cyanide bridges in magnetism and synthesis, an azido-cyanide mixed-bridged octanuclear [FeIII4NiII4] SMM of [{(enbzpy)Ni2(μ1,1-N3)2·(DMF)}{Tp∗Fe(CN)3}2]2·2DMF·14H2O (1) was explored and characterized, which exhibits slow relaxation of the magnetization and an S = 6 ground state benefit from the end-on azido bridges.

AB - Taking advantages of both azide and cyanide bridges in magnetism and synthesis, an azido-cyanide mixed-bridged octanuclear [FeIII4NiII4] SMM of [{(enbzpy)Ni2(μ1,1-N3)2·(DMF)}{Tp∗Fe(CN)3}2]2·2DMF·14H2O (1) was explored and characterized, which exhibits slow relaxation of the magnetization and an S = 6 ground state benefit from the end-on azido bridges.

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JO - Inorganic Chemistry

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ER -

An Azido-Cyanide Mixed-Bridged [Fe₄Ni₄] Single-Molecule Magnet

Abstract

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