An alkali-ion insertion approach to structurally transform metal-organic frameworks

Yue Qiao Hu; Mu Qing Li; Teng Li; Yan Yan Wang; Zhiping Zheng; Yan Zhen Zheng

doi:10.1039/c6ce00540c

An alkali-ion insertion approach to structurally transform metal-organic frameworks

Yue Qiao Hu, Mu Qing Li, Teng Li, Yan Yan Wang, Zhiping Zheng, Yan Zhen Zheng

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The insertion of alkali metal ions into a prevalent lanthanide-carboxylate coordination motif in heterometallic 3d-4f metal-organic frameworks (MOFs) leads to new MOFs whose structures are sensitively dependent on the size of the alkali ions used and with significantly enhanced effective free crystallographic volume.

Original language	English (US)
Pages (from-to)	7680-7684
Number of pages	5
Journal	CrystEngComm
Volume	18
Issue number	40
DOIs	https://doi.org/10.1039/c6ce00540c
State	Published - 2016

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1039/c6ce00540c

Cite this

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title = "An alkali-ion insertion approach to structurally transform metal-organic frameworks",

abstract = "The insertion of alkali metal ions into a prevalent lanthanide-carboxylate coordination motif in heterometallic 3d-4f metal-organic frameworks (MOFs) leads to new MOFs whose structures are sensitively dependent on the size of the alkali ions used and with significantly enhanced effective free crystallographic volume.",

author = "Hu, {Yue Qiao} and Li, {Mu Qing} and Teng Li and Wang, {Yan Yan} and Zhiping Zheng and Zheng, {Yan Zhen}",

note = "Funding Information: This work was supported by 973 project (2012CB619402), NSFC (21473129), Nation 1000 Young Talents program, Wuhan National High Magnetic Field Center (2015KF06) and the Fundamental Research Funds for the Central Universities. Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6ce00540c",

language = "English (US)",

volume = "18",

pages = "7680--7684",

journal = "CrystEngComm",

issn = "1466-8033",

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T1 - An alkali-ion insertion approach to structurally transform metal-organic frameworks

AU - Hu, Yue Qiao

AU - Li, Mu Qing

AU - Li, Teng

AU - Wang, Yan Yan

AU - Zheng, Zhiping

AU - Zheng, Yan Zhen

N1 - Funding Information: This work was supported by 973 project (2012CB619402), NSFC (21473129), Nation 1000 Young Talents program, Wuhan National High Magnetic Field Center (2015KF06) and the Fundamental Research Funds for the Central Universities. Publisher Copyright: © 2016 The Royal Society of Chemistry.

PY - 2016

Y1 - 2016

N2 - The insertion of alkali metal ions into a prevalent lanthanide-carboxylate coordination motif in heterometallic 3d-4f metal-organic frameworks (MOFs) leads to new MOFs whose structures are sensitively dependent on the size of the alkali ions used and with significantly enhanced effective free crystallographic volume.

AB - The insertion of alkali metal ions into a prevalent lanthanide-carboxylate coordination motif in heterometallic 3d-4f metal-organic frameworks (MOFs) leads to new MOFs whose structures are sensitively dependent on the size of the alkali ions used and with significantly enhanced effective free crystallographic volume.

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U2 - 10.1039/c6ce00540c

DO - 10.1039/c6ce00540c

M3 - Article

AN - SCOPUS:84991624861

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EP - 7684

JO - CrystEngComm

JF - CrystEngComm

IS - 40

ER -

An alkali-ion insertion approach to structurally transform metal-organic frameworks

Abstract

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CCDC 1419823: Experimental Crystal Structure Determination

CCDC 1419822: Experimental Crystal Structure Determination

CCDC 1419817: Experimental Crystal Structure Determination

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An alkali-ion insertion approach to structurally transform metal-organic frameworks

Abstract

ASJC Scopus subject areas

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Datasets

CCDC 1419823: Experimental Crystal Structure Determination

CCDC 1419822: Experimental Crystal Structure Determination

CCDC 1419817: Experimental Crystal Structure Determination

Cite this