Abstract
Acetonitrile bound to and activated by the Lewis acidic [Re6(μ3-Se)8]2+ cluster core was transformed into acetamidine in quantitative yield using NH3 as the nucleophile at room temperature. The amidine ligand was removed by treating the cluster-acetamidine complexes with trifluoroacetic acid in CH3CN, affording amidinium trifluoroacetate and the starting acetonitrile complexes.
Original language | English (US) |
---|---|
Pages (from-to) | 9505-9508 |
Number of pages | 4 |
Journal | Inorganic Chemistry |
Volume | 55 |
Issue number | 19 |
DOIs | |
State | Published - Oct 3 2016 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
Fingerprint
Dive into the research topics of 'Amidine Production by the Addition of NH3 to Nitrile(s) Bound to and Activated by the Lewis Acidic [Re6(μ3-Se)8]2+ Cluster Core'. Together they form a unique fingerprint.Datasets
-
CCDC 1034326: Experimental Crystal Structure Determination
Corbin, W. C. (Creator), Nichol, G. S. (Creator) & Zheng, Z. (Creator), Cambridge Crystallographic Data Centre, 2016
DOI: 10.5517/ccdc.csd.cc13q9ch, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc13q9ch&sid=DataCite
Dataset
-
CCDC 1034324: Experimental Crystal Structure Determination
Corbin, W. C. (Creator), Nichol, G. S. (Creator) & Zheng, Z. (Creator), Cambridge Crystallographic Data Centre, 2016
DOI: 10.5517/ccdc.csd.cc13q99f, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc13q99f&sid=DataCite
Dataset
-
CCDC 1034325: Experimental Crystal Structure Determination
Corbin, W. C. (Creator), Nichol, G. S. (Creator) & Zheng, Z. (Creator), Cambridge Crystallographic Data Centre, 2016
DOI: 10.5517/ccdc.csd.cc13q9bg, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc13q9bg&sid=DataCite
Dataset