Alcohol addition to acetonitrile activated by the [Re6(μ 3-Se)8]2+ cluster core

Peter Orto; Hugh D. Selby; Daniel Ferris; Jenine R. Maeyer; Zhiping Zheng

doi:10.1021/ic7004985

Alcohol addition to acetonitrile activated by the [Re₆(μ ₃-Se)₈]²⁺ cluster core

Peter Orto, Hugh D. Selby, Daniel Ferris, Jenine R. Maeyer, Zhiping Zheng

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

The addition of methanol and ethanol to the previously reported cluster solvates [Re₆(μ₃-Se)₈(PEt₃) ₅(MeCN)](SbF₆)₂ and trans-[Re ₆-(μ₃-Se)₈(PEt₃) ₄(CH₃CN)₂][SbF₆]₂ afforded three cluster complexes with imino ester ligands: {Re ₆(μ₃-Se)₈(PEt₃) ₅[HN=C(OCH₃)-(CH₃)]}(SbF₆) ₂, {Re₆(μ₃-Se)₈(PEt ₃)₅[HN=C(OCH₂CH₃)(CH ₃)]}-{SbF₆}₂, and trans-{Re₆(μ ₃-Se)₈(PEt₃)₄[HN=C(OCH ₃)(CH₃)]₂}-{SbF₆}₂. In all cases, predominant formation of the Z isomers was observed.

Original language	English (US)
Pages (from-to)	4377-4379
Number of pages	3
Journal	Inorganic Chemistry
Volume	46
Issue number	11
DOIs	https://doi.org/10.1021/ic7004985
State	Published - May 28 2007

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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@article{4503eef1053349c28042c10e45f63b37,

title = "Alcohol addition to acetonitrile activated by the [Re6(μ 3-Se)8]2+ cluster core",

abstract = "The addition of methanol and ethanol to the previously reported cluster solvates [Re6(μ3-Se)8(PEt3) 5(MeCN)](SbF6)2 and trans-[Re 6-(μ3-Se)8(PEt3) 4(CH3CN)2][SbF6]2 afforded three cluster complexes with imino ester ligands: {Re 6(μ3-Se)8(PEt3) 5[HN=C(OCH3)-(CH3)]}(SbF6) 2, {Re6(μ3-Se)8(PEt 3)5[HN=C(OCH2CH3)(CH 3)]}-{SbF6}2, and trans-{Re6(μ 3-Se)8(PEt3)4[HN=C(OCH 3)(CH3)]2}-{SbF6}2. In all cases, predominant formation of the Z isomers was observed.",

author = "Peter Orto and Selby, {Hugh D.} and Daniel Ferris and Maeyer, {Jenine R.} and Zhiping Zheng",

year = "2007",

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doi = "10.1021/ic7004985",

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journal = "Inorganic Chemistry",

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T1 - Alcohol addition to acetonitrile activated by the [Re6(μ 3-Se)8]2+ cluster core

AU - Orto, Peter

AU - Selby, Hugh D.

AU - Ferris, Daniel

AU - Maeyer, Jenine R.

AU - Zheng, Zhiping

PY - 2007/5/28

Y1 - 2007/5/28

N2 - The addition of methanol and ethanol to the previously reported cluster solvates [Re6(μ3-Se)8(PEt3) 5(MeCN)](SbF6)2 and trans-[Re 6-(μ3-Se)8(PEt3) 4(CH3CN)2][SbF6]2 afforded three cluster complexes with imino ester ligands: {Re 6(μ3-Se)8(PEt3) 5[HN=C(OCH3)-(CH3)]}(SbF6) 2, {Re6(μ3-Se)8(PEt 3)5[HN=C(OCH2CH3)(CH 3)]}-{SbF6}2, and trans-{Re6(μ 3-Se)8(PEt3)4[HN=C(OCH 3)(CH3)]2}-{SbF6}2. In all cases, predominant formation of the Z isomers was observed.

AB - The addition of methanol and ethanol to the previously reported cluster solvates [Re6(μ3-Se)8(PEt3) 5(MeCN)](SbF6)2 and trans-[Re 6-(μ3-Se)8(PEt3) 4(CH3CN)2][SbF6]2 afforded three cluster complexes with imino ester ligands: {Re 6(μ3-Se)8(PEt3) 5[HN=C(OCH3)-(CH3)]}(SbF6) 2, {Re6(μ3-Se)8(PEt 3)5[HN=C(OCH2CH3)(CH 3)]}-{SbF6}2, and trans-{Re6(μ 3-Se)8(PEt3)4[HN=C(OCH 3)(CH3)]2}-{SbF6}2. In all cases, predominant formation of the Z isomers was observed.

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 11

ER -

Alcohol addition to acetonitrile activated by the [Re₆(μ ₃-Se)₈]²⁺ cluster core

Abstract

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