A symbol approach for classification of molecule-based magnetic materials exemplified by coordination polymers of metal carboxylates

The ever-growing family of molecule-based magnetic materials calls for a systematic classification of these structurally sophisticated and magnetically diverse compounds. Using magnetically active coordination polymers of metal carboxylates as representatives, we propose and illustrate in this review a symbol approach for their organization and categorization. By adopting this approach, the seemingly complex magneto-structural correlations in a wide variety of molecular magnetic materials, including single-molecule magnets, single-chain magnets, geometrically frustrated magnets, and high Curie-temperature magnets, can be readily discerned.