Abstract
The amine has landed! By employing the rhodium catalyst [Rh 2(esp)2] in the presence of a readily available amine source (DPH), unactivated and styrene-type olefins can now be stereospecifally transformed, in high yields at room temperature, into valuable NH aziridine products. esp=α,α,α?,α?-tetramethyl-1,3- benzenedipropionic acid.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 4278-4280 |
| Number of pages | 3 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 53 |
| Issue number | 17 |
| DOIs | |
| State | Published - Apr 22 2014 |
| Externally published | Yes |
Keywords
- aziridination
- aziridines
- heterocycles
- nitrene
- rhodium
ASJC Scopus subject areas
- Catalysis
- General Chemistry
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