A mixed-valence bis(diarylamino)stilbene: Crystal structure and comparison of electronic coupling with biphenyl and tolane analogues

Stephen Barlow; Chad Risko; Veaceslav Coropceanu; Neil M. Tucker; Simon C. Jones; Zerubba Levi; Viktor N. Khrustalev; Mikhail Yu Antipin; Tiffany L. Kinnibrugh; Tatiana Timofeeva; Seth R. Marder; Jean Luc Brédas

doi:10.1039/b415018j

A mixed-valence bis(diarylamino)stilbene: Crystal structure and comparison of electronic coupling with biphenyl and tolane analogues

Stephen Barlow, Chad Risko, Veaceslav Coropceanu, Neil M. Tucker, Simon C. Jones, Zerubba Levi, Viktor N. Khrustalev, Mikhail Yu Antipin, Tiffany L. Kinnibrugh, Tatiana Timofeeva, Seth R. Marder, Jean Luc Brédas

Research output: Contribution to journal › Article › peer-review

55 Scopus citations

Abstract

The E-4,4′-bis[di(p-anisyl)amino]stilbene cation is a class-III mixed-valence species with electronic coupling comparable to that in its biphenyl-bridged analogue, whereas its tolane-bridged analogue belongs to class II.

Original language	English (US)
Pages (from-to)	764-766
Number of pages	3
Journal	Chemical Communications
Issue number	6
DOIs	https://doi.org/10.1039/b415018j
State	Published - Feb 14 2005
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b415018j

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Barlow, S., Risko, C., Coropceanu, V., Tucker, N. M., Jones, S. C., Levi, Z., Khrustalev, V. N., Antipin, M. Y., Kinnibrugh, T. L., Timofeeva, T., Marder, S. R., & Brédas, J. L. (2005). A mixed-valence bis(diarylamino)stilbene: Crystal structure and comparison of electronic coupling with biphenyl and tolane analogues. Chemical Communications, (6), 764-766. https://doi.org/10.1039/b415018j

Barlow, S, Risko, C, Coropceanu, V, Tucker, NM, Jones, SC, Levi, Z, Khrustalev, VN, Antipin, MY, Kinnibrugh, TL, Timofeeva, T, Marder, SR & Brédas, JL 2005, 'A mixed-valence bis(diarylamino)stilbene: Crystal structure and comparison of electronic coupling with biphenyl and tolane analogues', Chemical Communications, no. 6, pp. 764-766. https://doi.org/10.1039/b415018j

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author = "Stephen Barlow and Chad Risko and Veaceslav Coropceanu and Tucker, {Neil M.} and Jones, {Simon C.} and Zerubba Levi and Khrustalev, {Viktor N.} and Antipin, {Mikhail Yu} and Kinnibrugh, {Tiffany L.} and Tatiana Timofeeva and Marder, {Seth R.} and Br{\'e}das, {Jean Luc}",

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AU - Risko, Chad

AU - Coropceanu, Veaceslav

AU - Tucker, Neil M.

AU - Jones, Simon C.

AU - Levi, Zerubba

AU - Khrustalev, Viktor N.

AU - Antipin, Mikhail Yu

AU - Kinnibrugh, Tiffany L.

AU - Timofeeva, Tatiana

AU - Marder, Seth R.

AU - Brédas, Jean Luc

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AB - The E-4,4′-bis[di(p-anisyl)amino]stilbene cation is a class-III mixed-valence species with electronic coupling comparable to that in its biphenyl-bridged analogue, whereas its tolane-bridged analogue belongs to class II.

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A mixed-valence bis(diarylamino)stilbene: Crystal structure and comparison of electronic coupling with biphenyl and tolane analogues

Abstract

ASJC Scopus subject areas

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CCDC 252359: Experimental Crystal Structure Determination

CCDC 252360: Experimental Crystal Structure Determination

Cite this

A mixed-valence bis(diarylamino)stilbene: Crystal structure and comparison of electronic coupling with biphenyl and tolane analogues

Abstract

ASJC Scopus subject areas

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Datasets

CCDC 252359: Experimental Crystal Structure Determination

CCDC 252360: Experimental Crystal Structure Determination

Cite this