A Mixed-Ligand Approach for a Gigantic and Hollow Heterometallic Cage {Ni64RE96} for Gas Separation and Magnetic Cooling Applications

Wei Peng Chen; Pei Qin Liao; Youzhu Yu; Zhiping Zheng; Xiao Ming Chen; Yan Zhen Zheng

doi:10.1002/anie.201603907

A Mixed-Ligand Approach for a Gigantic and Hollow Heterometallic Cage {Ni₆₄RE₉₆} for Gas Separation and Magnetic Cooling Applications

Wei Peng Chen, Pei Qin Liao, Youzhu Yu, Zhiping Zheng, Xiao Ming Chen, Yan Zhen Zheng

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

126 Scopus citations

Abstract

Nanosized aggregations of metal ions shielded by organic ligands possessing both exquisite structural aesthetics and intriguing properties are fundamentally interesting. Three isostructural gigantic transition-metal–rare-earth heterometallic coordination cages are reported, abbreviated as {Ni₆₄RE₉₆} (RE=Gd, Dy, and Y) and obtained by a mixed-ligand approach, each possessing a cuboidal framework made of 160 metal ions and a nanosized spherical cavity in the center. Along with the structural novelty, these hollow cages show highly selective adsorptions for CO₂over CH₄or N₂at ambient temperatures. Moreover, the gadolinium analogue exhibits large magnetocaloric effect at ultralow temperatures.

Original language	English (US)
Pages (from-to)	9375-9379
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	55
Issue number	32
DOIs	https://doi.org/10.1002/anie.201603907
State	Published - Aug 2016

Keywords

cluster complexes
coordination cages
gas separation
magnetic cooling
rare-earth elements

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.201603907

Cite this

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title = "A Mixed-Ligand Approach for a Gigantic and Hollow Heterometallic Cage {Ni64RE96} for Gas Separation and Magnetic Cooling Applications",

abstract = "Nanosized aggregations of metal ions shielded by organic ligands possessing both exquisite structural aesthetics and intriguing properties are fundamentally interesting. Three isostructural gigantic transition-metal–rare-earth heterometallic coordination cages are reported, abbreviated as {Ni64RE96} (RE=Gd, Dy, and Y) and obtained by a mixed-ligand approach, each possessing a cuboidal framework made of 160 metal ions and a nanosized spherical cavity in the center. Along with the structural novelty, these hollow cages show highly selective adsorptions for CO2over CH4or N2at ambient temperatures. Moreover, the gadolinium analogue exhibits large magnetocaloric effect at ultralow temperatures.",

keywords = "cluster complexes, coordination cages, gas separation, magnetic cooling, rare-earth elements",

author = "Chen, {Wei Peng} and Liao, {Pei Qin} and Youzhu Yu and Zhiping Zheng and Chen, {Xiao Ming} and Zheng, {Yan Zhen}",

note = "Funding Information: This work was supported by NSFC (21473129), “National Young 1000-Plan” program and Wuhan National High Magnetic Field Center (2015KF06). We are grateful for Prof. Dr. Jie-Peng Zhang (Sun Yat-Sen University) and Dr. Yanyan Wang for significant discussions. Publisher Copyright: {\textcopyright} 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",

year = "2016",

month = aug,

doi = "10.1002/anie.201603907",

language = "English (US)",

volume = "55",

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AU - Chen, Wei Peng

AU - Liao, Pei Qin

AU - Yu, Youzhu

AU - Zheng, Zhiping

AU - Chen, Xiao Ming

AU - Zheng, Yan Zhen

N1 - Funding Information: This work was supported by NSFC (21473129), “National Young 1000-Plan” program and Wuhan National High Magnetic Field Center (2015KF06). We are grateful for Prof. Dr. Jie-Peng Zhang (Sun Yat-Sen University) and Dr. Yanyan Wang for significant discussions. Publisher Copyright: © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

PY - 2016/8

Y1 - 2016/8

N2 - Nanosized aggregations of metal ions shielded by organic ligands possessing both exquisite structural aesthetics and intriguing properties are fundamentally interesting. Three isostructural gigantic transition-metal–rare-earth heterometallic coordination cages are reported, abbreviated as {Ni64RE96} (RE=Gd, Dy, and Y) and obtained by a mixed-ligand approach, each possessing a cuboidal framework made of 160 metal ions and a nanosized spherical cavity in the center. Along with the structural novelty, these hollow cages show highly selective adsorptions for CO2over CH4or N2at ambient temperatures. Moreover, the gadolinium analogue exhibits large magnetocaloric effect at ultralow temperatures.

AB - Nanosized aggregations of metal ions shielded by organic ligands possessing both exquisite structural aesthetics and intriguing properties are fundamentally interesting. Three isostructural gigantic transition-metal–rare-earth heterometallic coordination cages are reported, abbreviated as {Ni64RE96} (RE=Gd, Dy, and Y) and obtained by a mixed-ligand approach, each possessing a cuboidal framework made of 160 metal ions and a nanosized spherical cavity in the center. Along with the structural novelty, these hollow cages show highly selective adsorptions for CO2over CH4or N2at ambient temperatures. Moreover, the gadolinium analogue exhibits large magnetocaloric effect at ultralow temperatures.

KW - cluster complexes

KW - coordination cages

KW - gas separation

KW - magnetic cooling

KW - rare-earth elements

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A Mixed-Ligand Approach for a Gigantic and Hollow Heterometallic Cage {Ni₆₄RE₉₆} for Gas Separation and Magnetic Cooling Applications

Abstract

Keywords

ASJC Scopus subject areas

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CCDC 1034662: Experimental Crystal Structure Determination

CCDC 1402448: Experimental Crystal Structure Determination

CCDC 1034661: Experimental Crystal Structure Determination

Cite this

A Mixed-Ligand Approach for a Gigantic and Hollow Heterometallic Cage {Ni64RE96} for Gas Separation and Magnetic Cooling Applications

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 1034662: Experimental Crystal Structure Determination

CCDC 1402448: Experimental Crystal Structure Determination

CCDC 1034661: Experimental Crystal Structure Determination

Cite this

A Mixed-Ligand Approach for a Gigantic and Hollow Heterometallic Cage {Ni₆₄RE₉₆} for Gas Separation and Magnetic Cooling Applications