A microchemical study of gas-phase kinetics for three irreversible reactions

D. G. Retzloff; B. M. Coull; J. Coull

doi:10.1021/j100706a007

A microchemical study of gas-phase kinetics for three irreversible reactions

D. G. Retzloff, B. M. Coull, J. Coull

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

In this work a comparison is made between reliable macroscopic measurements of the homogeneous reaction kinetics for the systems vinylcyclopropane and di-t-butyl peroxide and the microreaction measurements for these two systems over a higher temperature range, as a test for the reliability of the latter technique. Extension to the measurement of kinetic parameters for the system 2,3-dihydropyran is also considered.

Original language	English (US)
Pages (from-to)	2455-2459
Number of pages	5
Journal	Journal of physical chemistry
Volume	74
Issue number	12
DOIs	https://doi.org/10.1021/j100706a007
State	Published - 1970
Externally published	Yes

ASJC Scopus subject areas

General Engineering
Physical and Theoretical Chemistry

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10.1021/j100706a007

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title = "A microchemical study of gas-phase kinetics for three irreversible reactions",

abstract = "In this work a comparison is made between reliable macroscopic measurements of the homogeneous reaction kinetics for the systems vinylcyclopropane and di-t-butyl peroxide and the microreaction measurements for these two systems over a higher temperature range, as a test for the reliability of the latter technique. Extension to the measurement of kinetic parameters for the system 2,3-dihydropyran is also considered.",

author = "Retzloff, \{D. G.\} and Coull, \{B. M.\} and J. Coull",

year = "1970",

doi = "10.1021/j100706a007",

language = "English (US)",

volume = "74",

pages = "2455--2459",

journal = "Journal of physical chemistry",

issn = "0022-3654",

publisher = "American Chemical Society",

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T1 - A microchemical study of gas-phase kinetics for three irreversible reactions

AU - Retzloff, D. G.

AU - Coull, B. M.

AU - Coull, J.

PY - 1970

Y1 - 1970

N2 - In this work a comparison is made between reliable macroscopic measurements of the homogeneous reaction kinetics for the systems vinylcyclopropane and di-t-butyl peroxide and the microreaction measurements for these two systems over a higher temperature range, as a test for the reliability of the latter technique. Extension to the measurement of kinetic parameters for the system 2,3-dihydropyran is also considered.

AB - In this work a comparison is made between reliable macroscopic measurements of the homogeneous reaction kinetics for the systems vinylcyclopropane and di-t-butyl peroxide and the microreaction measurements for these two systems over a higher temperature range, as a test for the reliability of the latter technique. Extension to the measurement of kinetic parameters for the system 2,3-dihydropyran is also considered.

UR - https://www.scopus.com/pages/publications/0000816163

UR - https://www.scopus.com/inward/citedby.url?scp=0000816163&partnerID=8YFLogxK

U2 - 10.1021/j100706a007

DO - 10.1021/j100706a007

M3 - Article

AN - SCOPUS:0000816163

SN - 0022-3654

VL - 74

SP - 2455

EP - 2459

JO - Journal of physical chemistry

JF - Journal of physical chemistry

IS - 12

ER -

A microchemical study of gas-phase kinetics for three irreversible reactions

Abstract

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