A facile synthesis of α-phosphono esters through methoxycarbonylation of α-phosphono carbanions

Jon K.F. Geirsson; Jon T. Njardarson

doi:10.1016/0040-4039(94)88430-7

A facile synthesis of α-phosphono esters through methoxycarbonylation of α-phosphono carbanions

Jon K.F. Geirsson, Jon T. Njardarson

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

This paper describes a concise and effective synthesis of methyl α-phosphonoaryl acetates, effected by reacting α-phosphono carbanions with methyl chloroformate. Yields are high, and the purification of the products is readily achieved with column chromatography.

Original language	English (US)
Pages (from-to)	9071-9072
Number of pages	2
Journal	Tetrahedron Letters
Volume	35
Issue number	48
DOIs	https://doi.org/10.1016/0040-4039(94)88430-7
State	Published - Nov 28 1994
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/0040-4039(94)88430-7

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@article{33b34981a0f84ce1881c6c17bfdc249a,

title = "A facile synthesis of α-phosphono esters through methoxycarbonylation of α-phosphono carbanions",

abstract = "This paper describes a concise and effective synthesis of methyl α-phosphonoaryl acetates, effected by reacting α-phosphono carbanions with methyl chloroformate. Yields are high, and the purification of the products is readily achieved with column chromatography.",

author = "Geirsson, {Jon K.F.} and Njardarson, {Jon T.}",

year = "1994",

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doi = "10.1016/0040-4039(94)88430-7",

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journal = "Tetrahedron Letters",

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T1 - A facile synthesis of α-phosphono esters through methoxycarbonylation of α-phosphono carbanions

AU - Geirsson, Jon K.F.

AU - Njardarson, Jon T.

PY - 1994/11/28

Y1 - 1994/11/28

N2 - This paper describes a concise and effective synthesis of methyl α-phosphonoaryl acetates, effected by reacting α-phosphono carbanions with methyl chloroformate. Yields are high, and the purification of the products is readily achieved with column chromatography.

AB - This paper describes a concise and effective synthesis of methyl α-phosphonoaryl acetates, effected by reacting α-phosphono carbanions with methyl chloroformate. Yields are high, and the purification of the products is readily achieved with column chromatography.

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UR - http://www.scopus.com/inward/citedby.url?scp=0028079794&partnerID=8YFLogxK

U2 - 10.1016/0040-4039(94)88430-7

DO - 10.1016/0040-4039(94)88430-7

M3 - Article

AN - SCOPUS:0028079794

SN - 0040-4039

VL - 35

SP - 9071

EP - 9072

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 48

ER -

A facile synthesis of α-phosphono esters through methoxycarbonylation of α-phosphono carbanions

Abstract

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