A chiral 60-metal sodalite cage featuring 24 vertex-sharing [Er 4(μ 3-OH) 4] cubanes

Xlang Jlan Kong; Ylnglan Wu; La Sheng Long; Lan Sun Zheng; Zhiplng Zheng

doi:10.1021/ja901214d

A chiral 60-metal sodalite cage featuring 24 vertex-sharing [Er ₄(μ ₃-OH) ₄] cubanes

Xlang Jlan Kong, Ylnglan Wu, La Sheng Long, Lan Sun Zheng, Zhiplng Zheng

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

251 Scopus citations

Abstract

A chiral, cagelike, high-nuclearity lanthanide hydroxide cluster containing 60 Er(III) ions is reported. The cluster core possesses a fascinating sodalite-like structure with 24 vertex-sharing cubane-like [Er4(μ3-OH)4]8+ units. The hexagonal face of the sodalite cage features a templating μ ₆-CO ₃ ^2- ion. Magnetic studies revealed weak antiferromagnetic interactions.

Original language	English (US)
Pages (from-to)	6918-6919
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	20
DOIs	https://doi.org/10.1021/ja901214d
State	Published - May 27 2009

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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abstract = "A chiral, cagelike, high-nuclearity lanthanide hydroxide cluster containing 60 Er(III) ions is reported. The cluster core possesses a fascinating sodalite-like structure with 24 vertex-sharing cubane-like [Er4(μ3-OH)4]8+ units. The hexagonal face of the sodalite cage features a templating μ 6-CO 3 2- ion. Magnetic studies revealed weak antiferromagnetic interactions.",

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AU - Wu, Ylnglan

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AU - Zheng, Lan Sun

AU - Zheng, Zhiplng

PY - 2009/5/27

Y1 - 2009/5/27

N2 - A chiral, cagelike, high-nuclearity lanthanide hydroxide cluster containing 60 Er(III) ions is reported. The cluster core possesses a fascinating sodalite-like structure with 24 vertex-sharing cubane-like [Er4(μ3-OH)4]8+ units. The hexagonal face of the sodalite cage features a templating μ 6-CO 3 2- ion. Magnetic studies revealed weak antiferromagnetic interactions.

AB - A chiral, cagelike, high-nuclearity lanthanide hydroxide cluster containing 60 Er(III) ions is reported. The cluster core possesses a fascinating sodalite-like structure with 24 vertex-sharing cubane-like [Er4(μ3-OH)4]8+ units. The hexagonal face of the sodalite cage features a templating μ 6-CO 3 2- ion. Magnetic studies revealed weak antiferromagnetic interactions.

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A chiral 60-metal sodalite cage featuring 24 vertex-sharing [Er ₄(μ ₃-OH) ₄] cubanes

Abstract

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