Abstract
A chiral, cagelike, high-nuclearity lanthanide hydroxide cluster containing 60 Er(III) ions is reported. The cluster core possesses a fascinating sodalite-like structure with 24 vertex-sharing cubane-like [Er4(μ3-OH)4]8+ units. The hexagonal face of the sodalite cage features a templating μ 6-CO 3 2- ion. Magnetic studies revealed weak antiferromagnetic interactions.
Original language | English (US) |
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Pages (from-to) | 6918-6919 |
Number of pages | 2 |
Journal | Journal of the American Chemical Society |
Volume | 131 |
Issue number | 20 |
DOIs | |
State | Published - May 27 2009 |
ASJC Scopus subject areas
- Catalysis
- General Chemistry
- Biochemistry
- Colloid and Surface Chemistry
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CCDC 739276: Experimental Crystal Structure Determination
Kong, X.-J. (Creator), Wu, Y. (Creator), Long, L.-S. (Creator), Zheng, L.-S. (Creator) & Zheng, Z. (Creator), Cambridge Crystallographic Data Centre, 2010
DOI: 10.5517/ccst8mg, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccst8mg&sid=DataCite
Dataset
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CCDC 739277: Experimental Crystal Structure Determination
Kong, X.-J. (Creator), Wu, Y. (Creator), Long, L.-S. (Creator), Zheng, L.-S. (Creator) & Zheng, Z. (Creator), Cambridge Crystallographic Data Centre, 2010
DOI: 10.5517/ccst8nh, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccst8nh&sid=DataCite
Dataset
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CCDC 739278: Experimental Crystal Structure Determination
Kong, X.-J. (Creator), Wu, Y. (Creator), Long, L.-S. (Creator), Zheng, L.-S. (Creator) & Zheng, Z. (Creator), Cambridge Crystallographic Data Centre, 2010
DOI: 10.5517/ccst8pj, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccst8pj&sid=DataCite
Dataset