3.14 Synthetically Derived Chiral Auxiliaries: Uses of Derivatives of Non-Carbohydrate Aldehydes and Ketones in Asymmetric Synthesis

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

This chapter presents the uses of noncarbohydrate aldehydes and ketones as chiral auxiliaries. These auxiliaries have principally been used as components of acetals and ketals for modification of the diol component. Some coverage of thioketals, aminals, and imines is included. Acetals and ketals derived from carbohydrates, or from enantiomerically pure diols and the like, are not covered in this chapter.

Original languageEnglish (US)
Title of host publicationSynthetic Methods II - Chiral Auxiliaries
PublisherElsevier Ltd.
Pages377-407
Number of pages31
Volume3
ISBN (Print)9780080951683
DOIs
StatePublished - Sep 2012

Keywords

  • Asymmetric synthesis
  • Chiral acetal
  • Chiral auxiliary
  • Chiral ketal
  • Review

ASJC Scopus subject areas

  • General Chemistry

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