Abstract
In the title compound, C22H24N4O, the aromatic moiety is essentially planar (r.m.s. deviation of a least-squares plane fitted through all non-H atoms = 0.0386 Å) and is rotated by 89.98 (4)°from the piperazine ring, which adopts the expected chair conformation. The propanol chain is not fully extended away from the piperazine ring. In the crystal, there are two unique hydrogen-bonding interactions. One is an O-H⋯N interaction which, together with an inversion-related symmetry equivalent, forms a ring motif. The second is an N-H⋯N interaction which links adjacent molecules by means of a chain motif which propagates in the c-axis direction. Overall, a two-dimensional hydrogen-bonded structure is formed.
Original language | English (US) |
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Pages (from-to) | o3465-o3466 |
Journal | Acta Crystallographica Section E: Structure Reports Online |
Volume | 67 |
Issue number | 12 |
DOIs | |
State | Published - Dec 2011 |
Keywords
- R factor = 0.039
- T = 120 K
- data-to-parameter ratio = 10.1
- mean σ(C-C) = 0.003 Å
- single-crystal X-ray study
- wR factor = 0.108
ASJC Scopus subject areas
- General Chemistry
- General Materials Science
- Condensed Matter Physics
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CCDC 858523: Experimental Crystal Structure Determination
Nichol, G. S. (Creator), Boddupally, P. V. L. (Creator), De, B. (Creator) & Hurley, L. H. (Creator), Cambridge Crystallographic Data Centre, 2012
DOI: 10.5517/ccxtc9c, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccxtc9c&sid=DataCite
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