π-Stacked oligo(phenylene vinylene)s based on pseudo-geminal substituted [2.2]paracyclophanes: Impact of interchain geometry and interactions on the electronic properties

Sukrit Mukhopadhyay; Subodh P. Jagtap; Veaceslav Coropceanu; Jean Luc Brédas; David M. Collard

doi:10.1002/anie.201205738

π-Stacked oligo(phenylene vinylene)s based on pseudo-geminal substituted [2.2]paracyclophanes: Impact of interchain geometry and interactions on the electronic properties

Sukrit Mukhopadhyay
, Subodh P. Jagtap
, Veaceslav Coropceanu
, Jean Luc Brédas
, David M. Collard

Research output: Contribution to journal › Article › peer-review

49 Scopus citations

Abstract

A clever combination: A series of phenylene vinylene oligomers, in which the conjugated segments are held in a well-defined stacked arrangement along their entire length, was studied experimentally and theoretically (see picture). The impact of the extended interchain interactions on the photophysics of the π-stacked systems is reported.

Original language	English (US)
Pages (from-to)	11629-11632
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	46
DOIs	https://doi.org/10.1002/anie.201205738
State	Published - Nov 12 2012
Externally published	Yes

Keywords

conjugation
density functional calculations
photophysics
stacking interactions
π interactions

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.201205738

Cite this

π-Stacked oligo(phenylene vinylene)s based on pseudo-geminal substituted [2.2]paracyclophanes: Impact of interchain geometry and interactions on the electronic properties. / Mukhopadhyay, Sukrit; Jagtap, Subodh P.; Coropceanu, Veaceslav et al.
In: Angewandte Chemie - International Edition, Vol. 51, No. 46, 12.11.2012, p. 11629-11632.

Research output: Contribution to journal › Article › peer-review

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AU - Brédas, Jean Luc

AU - Collard, David M.

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π-Stacked oligo(phenylene vinylene)s based on pseudo-geminal substituted [2.2]paracyclophanes: Impact of interchain geometry and interactions on the electronic properties

Abstract

Keywords

ASJC Scopus subject areas

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