This dataset comprises raw LC-MS data generated from a study examining the root and rhizosphere metabolomes of of Lehmann lovegrass (Eragrostis lehmanniana) and Arizona cottontop (Digitaria californica) in both canopy and inter-canopy regions under velvet mesquite trees (Prosopis velutina) at the Santa Rita Experimental Range (SRER) in Arizona. Samples were collected from twelve 1m x 1m plots representing two dominant plant species (Lehmann lovegrass and Arizona cottontop) across two canopy conditions (closed and open), resulting in 36 root and rhizosphere samples.

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